P(C₆H₅)4⁽¹⁺⁾*Pt(NH₃)(Cl)3^(1-) = [P(C₆H₅)4][Pt(NH₃)(Cl)3]

Base Information

Chemical Name:P(C₆H₅)4⁽¹⁺⁾*Pt(NH₃)(Cl)3^(1-) = [P(C₆H₅)4][Pt(NH₃)(Cl)3]
CAS No.:110790-59-5
Molecular Formula:C₂₄H₂₀P*Cl₃H₃NPt
Molecular Weight:657.866
Hs Code.:

P(C<sub>6</sub>H<sub>5</sub>)4<sup>(1+)</sup>*Pt(NH<sub>3</sub>)(Cl)3<sup>(1-)</sup> = [P(C<sub>6</sub>H<sub>5</sub>)4][Pt(NH<sub>3</sub>)(Cl)3]

Synonyms:P(C₆H₅)4⁽¹⁺⁾*Pt(NH₃)(Cl)3^(1-) = [P(C₆H₅)4][Pt(NH₃)(Cl)3]

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Chemical Property of P(C₆H₅)4⁽¹⁺⁾*Pt(NH₃)(Cl)3^(1-) = [P(C₆H₅)4][Pt(NH₃)(Cl)3]

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Technology Process of P(C₆H₅)4⁽¹⁺⁾*Pt(NH₃)(Cl)3^(1-) = [P(C₆H₅)4][Pt(NH₃)(Cl)3]

There total 4 articles about P(C₆H₅)4⁽¹⁺⁾*Pt(NH₃)(Cl)3^(1-) = [P(C₆H₅)4][Pt(NH₃)(Cl)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 15663-27-1
cisplatin

: 68696-18-4
tetraethylammonium chloride monohydrate

: 2001-45-8
tetraphenyl phosphonium chloride

: 110790-59-5
P(C₆H₅)4⁽¹⁺⁾*Pt(NH₃)(Cl)3^(1-) = [P(C₆H₅)4][Pt(NH₃)(Cl)3]

Guidance literature:: In N,N-dimethyl acetamide; soln. of Pt compd. and NEt4Cl in Me2NCOMe is heated to 100(+-2)°C (6 h, N2-stream), cooled to room temp., MeCOOEt/C6H14 is added, mixt. is chilled (12 h at -10°C), oil is dissolved in H2O, filtn., Ph4PCl in H2O is added, stirred for 30 min; solid is collected, washed with water, dried in vac., recrystd. by chilling (-10°C) a CH2Cl2/ether soln.; elem. anal.;
DOI:10.1016/S0020-1693(00)87896-2

Reference yield: 52.0%

: 15663-27-1
cisplatin

: 2751-90-8
tetraphenylphosphonium bromide

: bis(tetraphenylphosphonium) tetrachloroplatinate(II)

: 110790-59-5
P(C₆H₅)4⁽¹⁺⁾*Pt(NH₃)(Cl)3^(1-) = [P(C₆H₅)4][Pt(NH₃)(Cl)3]

Guidance literature:: platinum; In hydrogenchloride; Pt-salt soln. refluxing with catalyst for 2 h, ppt. removal and washing(cold water), org. compd. addn. to filtrate and washings, mixt. stirring and cooling (2 h, 5°C), pptn.; ppt. washing (H2O, EtOH, ether), vac. drying, solid dissoln. (CH2Cl2), residual ppt. removal, ether addn., ppt. dissoln. in DMF, pptd. second product removal, filtrate vol. redn., pptn. on ethyl acetate addn., washing (ether), vac. drying; elem. anal.;
DOI:10.1016/0020-1693(95)04644-5

Reference yield: 52.0%

: 15663-27-1
cisplatin

: tetraethylammonium chloride hydrate

: 2001-45-8
tetraphenyl phosphonium chloride

: 110790-59-5
P(C₆H₅)4⁽¹⁺⁾*Pt(NH₃)(Cl)3^(1-) = [P(C₆H₅)4][Pt(NH₃)(Cl)3]

Guidance literature:: cisplatin; tetraethylammonium chloride hydrate; In N,N-dimethyl acetamide; at 100 ℃; for 6h; Inert atmosphere;

tetraphenyl phosphonium chloride; In water; at 20 ℃; for 1h;
DOI:10.1039/c8dt01583j