Cyclohexyloxy-diethyl-borane

Base Information

• Chemical Name: Cyclohexyloxy-diethyl-borane
• CAS No.: 108678-42-8
• Molecular Formula: C₁₀H₂₁BO
• Molecular Weight: 168.087
• Mol file: 108678-42-8.mol

Synonyms:Cyclohexyloxy-diethyl-borane

Chemical Property of Cyclohexyloxy-diethyl-borane

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of Cyclohexyloxy-diethyl-borane

There total 1 articles about Cyclohexyloxy-diethyl-borane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tricyclohexyl borate (2467-16-5) + ethylmagnesium bromide (925-90-6) → Cyclohexyloxy-diethyl-borane (108678-42-8)

Guidance literature:

In diethyl ether; byproducts: C2H5B(OC6H11)2; soln. of B-compd. cooled to -40°C, Grignard reagent added dropwise, stirred for 1h, terminated by addn. of HCl/Et2O; not isolated, monitored by 11B-NMR;

DOI:10.1021/om00038a024

Reference yield: 98.0%

Cyclohexyloxy-diethyl-borane (108678-42-8) + 2,4-pentane dione t butyl dimethyl silyl enol ether (69404-97-3) → 1-(tert-butyldimethylsiloxy)cyclohexane (67124-67-8)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In n-heptane; for 2h; Ambient temperature;

DOI:10.1055/s-1986-31703

Reference yield:

Cyclohexyloxy-diethyl-borane (108678-42-8) → O-cyclohexyl phenylphenylphosphinate (1706-93-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) Et₃N, acetylacetone / 1.) THF, -30 deg C, 2 h; 2.) 0 deg C, 2 h; RT, 5 h

2: 30percent H₂O₂ / acetone

With dihydrogen peroxide; triethylamine; acetylacetone; In acetone;

upstream raw materials:

tricyclohexyl borate

ethylmagnesium bromide

Downstream raw materials:

phosphorous acid diethyl ester-cyclohexyl ester

1-(tert-butyldimethylsiloxy)cyclohexane

cyclohexyl diphenylphosphinite

cyclohexyl diethyl phosphate