C₁₈H₃₂O₃Si

Base Information

Chemical Name:C₁₈H₃₂O₃Si
CAS No.:1207722-96-0
Molecular Formula:C₁₈H₃₂O₃Si
Molecular Weight:324.536
Hs Code.:

C<sub>18</sub>H<sub>32</sub>O<sub>3</sub>Si

Synonyms:C₁₈H₃₂O₃Si

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Chemical Property of C₁₈H₃₂O₃Si

Chemical Property:

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Technology Process of C₁₈H₃₂O₃Si

There total 1 articles about C₁₈H₃₂O₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 18742-02-4
2-bromo-2-(2-ethyl)dioxolane

: 75-77-4
chloro-trimethyl-silane

: 90528-94-2
(-)-(R)-5-methyl-2-allyl-2-cyclohexenone

: 1207722-96-0
C₁₈H₃₂O₃Si

Guidance literature:: 2-bromo-2-(2-ethyl)dioxolane; With iodine; magnesium; In tetrahydrofuran; at 25 ℃; Inert atmosphere;

With dmap; copper(I) bromide dimethylsulfide complex; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;

chloro-trimethyl-silane; (-)-(R)-5-methyl-2-allyl-2-cyclohexenone; In tetrahydrofuran; at -78 - -10 ℃; for 6h; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/jo9026534

Reference yield:

: 1207722-96-0
C₁₈H₃₂O₃Si

: C₂₄H₃₃NO₄S

Guidance literature:: Multi-step reaction with 8 steps

1: hydrogenchloride / tetrahydrofuran; water / 2.5 h / 20 °C / Inert atmosphere; Heating

2: pyridinium chlorochromate / dichloromethane / 4 h / 20 °C / Inert atmosphere

3: toluene-4-sulfonic acid / benzene / Inert atmosphere; Reflux

4: tetrahydrofuran / Inert atmosphere

5: pyridine; thionyl chloride / dichloromethane / Inert atmosphere

6: dihydrogen peroxide; 9-borabicyclo[3.3.1]nonane; sodium hydroxide / Inert atmosphere

7: 1H-imidazole; iodine; triphenylphosphine / Inert atmosphere

8: tetra-(n-butyl)ammonium iodide; sodium hydroxide / water; benzene / 2.5 h / 100 °C / Inert atmosphere

With pyridine; 1H-imidazole; hydrogenchloride; thionyl chloride; dihydrogen peroxide; iodine; tetra-(n-butyl)ammonium iodide; toluene-4-sulfonic acid; 9-borabicyclo[3.3.1]nonane; triphenylphosphine; pyridinium chlorochromate; sodium hydroxide; In tetrahydrofuran; dichloromethane; water; benzene; 1: Helquist annulation reaction;
DOI:10.1021/jo1023188

Reference yield:

: 1207722-96-0
C₁₈H₃₂O₃Si

: 18331-31-2
(-)-8-deoxyserratinine

Guidance literature:: Multi-step reaction with 15 steps

1: hydrogenchloride / tetrahydrofuran; water / 2.5 h / 20 °C / Inert atmosphere; Heating

2: pyridinium chlorochromate / dichloromethane / 4 h / 20 °C / Inert atmosphere

3: toluene-4-sulfonic acid / benzene / Inert atmosphere; Reflux

4: tetrahydrofuran / Inert atmosphere

5: pyridine; thionyl chloride / dichloromethane / Inert atmosphere

6: dihydrogen peroxide; 9-borabicyclo[3.3.1]nonane; sodium hydroxide / Inert atmosphere

7: 1H-imidazole; iodine; triphenylphosphine / Inert atmosphere

8: tetra-(n-butyl)ammonium iodide; sodium hydroxide / water; benzene / 2.5 h / 100 °C / Inert atmosphere

9: naphthalene; sodium / 1,2-dimethoxyethane / 2.5 h / 100 °C / Inert atmosphere

10: dmap / dichloromethane / Inert atmosphere

11: hydrogenchloride / Inert atmosphere

12: oxone; Shi's ketone; tetra(n-butyl)ammonium hydrogensulfate / Inert atmosphere

13: potassium hydroxide / methanol / Inert atmosphere; Reflux

14: Jones reagent / Inert atmosphere

15: sodium tetrahydroborate / ethanol / 0 °C / Inert atmosphere

With pyridine; 1H-imidazole; hydrogenchloride; dmap; sodium tetrahydroborate; Jones reagent; thionyl chloride; oxone; Shi's ketone; naphthalene; dihydrogen peroxide; iodine; tetra(n-butyl)ammonium hydrogensulfate; sodium; tetra-(n-butyl)ammonium iodide; toluene-4-sulfonic acid; 9-borabicyclo[3.3.1]nonane; triphenylphosphine; pyridinium chlorochromate; potassium hydroxide; sodium hydroxide; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; ethanol; dichloromethane; water; benzene; 1: Helquist annulation reaction / 12: Shi asymmetric epoxidation reaction / 14: Jones oxidation;
DOI:10.1021/jo1023188