1,2-bis(bis(3,4,5-trifluorophenyl)phosphino)ethane

Base Information

• Chemical Name: 1,2-bis(bis(3,4,5-trifluorophenyl)phosphino)ethane
• CAS No.: 903570-02-5
• Molecular Formula: C₂₆H₁₂F₁₂P₂
• Molecular Weight: 614.31
• Mol file: 903570-02-5.mol

Synonyms:1,2-bis(bis(3,4,5-trifluorophenyl)phosphino)ethane

Chemical Property of 1,2-bis(bis(3,4,5-trifluorophenyl)phosphino)ethane

Chemical Property:

Purity/Quality:

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Technology Process of 1,2-bis(bis(3,4,5-trifluorophenyl)phosphino)ethane

There total 1 articles about 1,2-bis(bis(3,4,5-trifluorophenyl)phosphino)ethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.6%

1,2-bis(dichlorophosphino)ethane (28240-69-9) + 3,4,5-trifluoro-1-bromobenzene (138526-69-9) → 1,2-bis(bis(3,4,5-trifluorophenyl)phosphino)ethane (903570-02-5)

Guidance literature:

3,4,5-trifluoro-1-bromobenzene; With magnesium; In diethyl ether;

1,2-bis(dichlorophosphino)ethane; for 1h; Further stages.; Heating;

DOI:10.1039/b603540j

Reference yield: 94.0%

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 1,2-bis(bis(3,4,5-trifluorophenyl)phosphino)ethane (903570-02-5) → (1,2-bis(bis(3,4,5-trifluorophenyl)phosphino)ethane)dichloroplatinum(II) (1243403-97-5)

Guidance literature:

In toluene; (Ar); soln. of ligand and Pt complex in toluene was stirred under refluxfor 12 h; cooled to room temp.; filtered; washed with Et2O in air; elem. anal.;

DOI:10.1021/om100073j

Reference yield: 79.0%

1,2-bis(bis(3,4,5-trifluorophenyl)phosphino)ethane (903570-02-5) + (bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) (12146-37-1,124717-04-0) → (1,2-bis(bis(3,4,5-trifluorophenyl)phosphino)ethane)tetracarbonylmolybdenum (1243403-66-8)

Guidance literature:

In 1,2-dichloro-ethane; (Ar); soln. of ligand and Mo complex in dichloroethane was stirred at 60°C for 3 h; filtered; concd. (vac.); recrystd. (CH2Cl2/hexane); elem. anal.;

DOI:10.1021/om100073j

upstream raw materials:

1,2-bis(dichlorophosphino)ethane

3,4,5-trifluoro-1-bromobenzene

Downstream raw materials:

(1,2-bis(bis(3,4,5-trifluorophenyl)phosphino)ethane)tetracarbonylmolybdenum

(1,2-bis(bis(3,4,5-trifluorophenyl)phosphino)ethane)dichloroplatinum(II)