trans-hydroxo(phenyl)bis(triphenylphosphine)platinum(II)

Base Information

Chemical Name:trans-hydroxo(phenyl)bis(triphenylphosphine)platinum(II)
CAS No.:60399-83-9
Molecular Formula:C₄₂H₃₆OP₂Pt
Molecular Weight:813.775
Hs Code.:

Synonyms:trans-hydroxo(phenyl)bis(triphenylphosphine)platinum(II)

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Chemical Property of trans-hydroxo(phenyl)bis(triphenylphosphine)platinum(II)

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Technology Process of trans-hydroxo(phenyl)bis(triphenylphosphine)platinum(II)

There total 1 articles about trans-hydroxo(phenyl)bis(triphenylphosphine)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 14104-20-2
silver tetrafluoroborate

: 18421-49-3
trans-Pt(phenyl)Cl(triphenylphosphine)2

: 60399-83-9
trans-hydroxo(phenyl)bis(triphenylphosphine)platinum(II)

Guidance literature:: With potassium hydroxide; In water; acetone; byproducts: AgCl; N2-atmosphere; stirring Pt-complex with equimolar amt. of AgBF4 (in Me2CO) for 3 h at room temp., filtration off of AgCl, addn. of slight excessof aq. KOH (stirring), standing at room temp. for 2 h; solvent removal (reduced pressure), extn. into C6H6, crystn. on concn. and hexane addn.; elem. anal.;
DOI:10.1039/DT9760000993

Reference yield: 89.0%

: 60399-83-9
trans-hydroxo(phenyl)bis(triphenylphosphine)platinum(II)

: 183387-28-2,135225-24-0
1,3,5,7,9,11,14-heptacyclopentyltricyclo[7.3.3.15,11]heptasiloxane-endo-3,7,14-triol

: trans-[Pt(Ph)(PPh₃)2((cyclo-C₅H₉)7Si₇O₁₀(OH)2)]

Guidance literature:: In benzene; byproducts: H2O; Ar or N2; ligand added to benzene soln. of Pt compd. (1:1 molar ratio), mixt. stirred at room temp. for 5 d; filtered, evapd., washed (hexane), dried (vac.);
DOI:10.1016/j.jorganchem.2011.09.023

Reference yield: 78.0%

: 75-91-2
tert.-butylhydroperoxide

: 60399-83-9
trans-hydroxo(phenyl)bis(triphenylphosphine)platinum(II)

: 87249-42-1
trans-[(PPh₃)2Pt(Ph)(tert-butylperoxo)]

Guidance literature:: In tetrahydrofuran; diethyl ether; under N2, Pt-complex suspended in THF-Et2O with stirring, 3.2 equiv of ligand added, stirred for 30 min; evapd. in vac., treated with Et2O-heptane under stirring, filtered, washed with heptane, dried in vac., recrystd. from benzene-heptane;