5,5'-((1,4-diazepane-1,4-diyl)bis(methylene))bis(3-tert-butyl)-2-hydroxybenzaldehyde

Base Information

• Chemical Name: 5,5'-((1,4-diazepane-1,4-diyl)bis(methylene))bis(3-tert-butyl)-2-hydroxybenzaldehyde
• CAS No.: 1415968-03-4
• Molecular Formula: C₂₉H₄₀N₂O₄
• Molecular Weight: 480.648
• Mol file: 1415968-03-4.mol

Synonyms:5,5'-((1,4-diazepane-1,4-diyl)bis(methylene))bis(3-tert-butyl)-2-hydroxybenzaldehyde

Chemical Property of 5,5'-((1,4-diazepane-1,4-diyl)bis(methylene))bis(3-tert-butyl)-2-hydroxybenzaldehyde

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,5'-((1,4-diazepane-1,4-diyl)bis(methylene))bis(3-tert-butyl)-2-hydroxybenzaldehyde

There total 1 articles about 5,5'-((1,4-diazepane-1,4-diyl)bis(methylene))bis(3-tert-butyl)-2-hydroxybenzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1,4-Diazacycloheptane (505-66-8) + 3-tert-butyl-5-(chloromethyl)-2-hydroxybenzaldehyde (183017-88-1) → 5,5'-((1,4-diazepane-1,4-diyl)bis(methylene))bis(3-tert-butyl)-2-hydroxybenzaldehyde (1415968-03-4)

Guidance literature:

In toluene; at 20 - 60 ℃; for 2h;

DOI:10.1016/j.molcata.2012.10.021

Reference yield:

5,5'-((1,4-diazepane-1,4-diyl)bis(methylene))bis(3-tert-butyl)-2-hydroxybenzaldehyde (1415968-03-4) + (R,R)-1,2-diphenylethylenediamine (35132-20-8) + manganese (II) acetate tetrahydrate (6156-78-1) → C43H50ClMnN4O2 + C86H100Cl2Mn2N8O4

Guidance literature:

5,5'-((1,4-diazepane-1,4-diyl)bis(methylene))bis(3-tert-butyl)-2-hydroxybenzaldehyde; (R,R)-1,2-diphenylethylenediamine; In tetrahydrofuran; at 20 ℃;

manganese (II) acetate tetrahydrate; In methanol; dichloromethane; at 60 ℃; for 6h; Inert atmosphere;

With lithium chloride; In methanol; dichloromethane; at 20 ℃; for 4h; Overall yield = 92 %; Overall yield = 0.31 g; Inert atmosphere;

DOI:10.1016/j.molcata.2012.10.021

Reference yield:

5,5'-((1,4-diazepane-1,4-diyl)bis(methylene))bis(3-tert-butyl)-2-hydroxybenzaldehyde (1415968-03-4) + (R,R)-1,2-diphenylethylenediamine (35132-20-8) → C43H52N4O2 + C86H104N8O4

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 2h; Overall yield = 80 %; Overall yield = 0.6 g;

DOI:10.1016/j.molcata.2012.10.021

upstream raw materials:

1,4-Diazacycloheptane

3-tert-butyl-5-(chloromethyl)-2-hydroxybenzaldehyde