(2-Bromophenethoxy)(tert-butyl)dimethylsilane

Base Information

Chemical Name:(2-Bromophenethoxy)(tert-butyl)dimethylsilane
CAS No.:181021-20-5
Molecular Formula:C14H23 Br O Si
Molecular Weight:315.326
Hs Code.:2931900090
DSSTox Substance ID:DTXSID40444525
Wikidata:Q82262682
Mol file:181021-20-5.mol

Synonyms:181021-20-5;(2-Bromophenethoxy)(tert-butyl)dimethylsilane;(2-Bromophenethoxy)(t-butyl)dimethylsilane;2-(2-bromophenyl)ethoxy-tert-butyl-dimethylsilane;2-(2-tert-Butyldimethylsilyloxyethyl)bromobenzene;[2-(2-bromophenyl)ethoxy](tert-butyl)dimethylsilane;SCHEMBL6347925;DTXSID40444525;Benzene,1-bromo-2-[2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethyl]-;MFCD09258648;AKOS015835147;BS-21779;2-Bromophenethyl alcohol, TBDMS derivative;CS-0211876;F74557;A881031;2-Bromophenethyl alcohol, tert-butyldimethylsilyl ether

Suppliers and Price of (2-Bromophenethoxy)(tert-butyl)dimethylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(2-Bromophenethoxy)(t-butyl)dimethylsilane
100mg
$ 60.00

TRC
(2-Bromophenethoxy)(t-butyl)dimethylsilane
250mg
$ 115.00

SynQuest Laboratories
2-(2-tert-Butyldimethylsilyloxyethyl)bromobenzene 98%
1 g
$ 192.00

Oakwood
(2-Bromophenethoxy)(tert-butyl)dimethylsilane
25g
$ 1695.00

Oakwood
(2-Bromophenethoxy)(tert-butyl)dimethylsilane
5g
$ 450.00

Oakwood
(2-Bromophenethoxy)(tert-butyl)dimethylsilane
1g
$ 110.00

Matrix Scientific
(2-Bromophenethoxy)(tert-butyl)dimethylsilane 95+%
1g
$ 118.00

Matrix Scientific
(2-Bromophenethoxy)(tert-butyl)dimethylsilane 95+%
5g
$ 468.00

Crysdot
(2-Bromophenethoxy)(tert-butyl)dimethylsilane 95+%
5g
$ 452.00

Chemenu
(2-Bromophenethoxy)(tert-butyl)dimethylsilane 95%
5g
$ 427.00

Total 11 raw suppliers

Chemical Property of (2-Bromophenethoxy)(tert-butyl)dimethylsilane

Chemical Property:

Vapor Pressure:0.001mmHg at 25°C
Boiling Point:314.9°Cat760mmHg
Flash Point:144.3°C
PSA：9.23000
Density:1.127g/cm³
LogP:5.01340
Storage Temp.:2-8°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:5
Exact Mass:314.07015
Heavy Atom Count:17
Complexity:235

Purity/Quality:

97% ^*data from raw suppliers

(2-Bromophenethoxy)(t-butyl)dimethylsilane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OCCC1=CC=CC=C1Br

Technology Process of (2-Bromophenethoxy)(tert-butyl)dimethylsilane

There total 2 articles about (2-Bromophenethoxy)(tert-butyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 1074-16-4
2-bromophenylethyl alcohol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 181021-20-5
2-(2-bromophenyl)-O-(tert-butyldimethylsilyl)ethan-2-ol

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 0 - 20 ℃;
DOI:10.1021/jo9605814

Reference yield:

: 18698-97-0
ortho-bromophenylacetic acid

: 181021-20-5
2-(2-bromophenyl)-O-(tert-butyldimethylsilyl)ethan-2-ol

Guidance literature:: Multi-step reaction with 2 steps

1: borane-THF / tetrahydrofuran / 12 h / 60 °C

2: 1H-imidazole / dichloromethane / 2 h / 20 °C

With 1H-imidazole; borane-THF; In tetrahydrofuran; dichloromethane;
DOI:10.1021/acs.jmedchem.0c01491

Reference yield: 99.0%

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 181021-20-5
2-(2-bromophenyl)-O-(tert-butyldimethylsilyl)ethan-2-ol

: 81168-10-7
2-<2-(t-Butyldimethylsilyloxy)ethyl>benzaldehyde

Guidance literature:: 2-(2-bromophenyl)-O-(tert-butyldimethylsilyl)ethan-2-ol; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.0833333h;

N,N-dimethyl-formamide; In tetrahydrofuran; hexane; at -78 ℃; for 0.166667h;
DOI:10.1021/acs.jmedchem.0c01491