1-((tert-butyldimethylsilyl)oxy)-2-(4-oxo-1-(propa-1,2-dien-1-yl)-cyclohexa-2,5-dien-1-yl)ethyl acetate

Base Information

Chemical Name:1-((tert-butyldimethylsilyl)oxy)-2-(4-oxo-1-(propa-1,2-dien-1-yl)-cyclohexa-2,5-dien-1-yl)ethyl acetate
CAS No.:1190958-17-8
Molecular Formula:C₁₉H₂₈O₄Si
Molecular Weight:348.514
Hs Code.:

Synonyms:1-((tert-butyldimethylsilyl)oxy)-2-(4-oxo-1-(propa-1,2-dien-1-yl)-cyclohexa-2,5-dien-1-yl)ethyl acetate

Suppliers and Price of 1-((tert-butyldimethylsilyl)oxy)-2-(4-oxo-1-(propa-1,2-dien-1-yl)-cyclohexa-2,5-dien-1-yl)ethyl acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-((tert-butyldimethylsilyl)oxy)-2-(4-oxo-1-(propa-1,2-dien-1-yl)-cyclohexa-2,5-dien-1-yl)ethyl acetate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-((tert-butyldimethylsilyl)oxy)-2-(4-oxo-1-(propa-1,2-dien-1-yl)-cyclohexa-2,5-dien-1-yl)ethyl acetate

There total 5 articles about 1-((tert-butyldimethylsilyl)oxy)-2-(4-oxo-1-(propa-1,2-dien-1-yl)-cyclohexa-2,5-dien-1-yl)ethyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 3240-34-4
[bis(acetoxy)iodo]benzene

: 1190958-14-5
4-(2-((tert-butyldimethylsilyl)oxy)pent-4-yn-1-yl)phenol

: 1190958-17-8
1-((tert-butyldimethylsilyl)oxy)-2-(4-oxo-1-(propa-1,2-dien-1-yl)-cyclohexa-2,5-dien-1-yl)ethyl acetate

Guidance literature:: In dichloromethane; 1,1,1,3',3',3'-hexafluoro-propanol; at -17 ℃;
DOI:10.1016/j.tet.2010.03.096

Reference yield: 40.0%

: 3240-34-4
[bis(acetoxy)iodo]benzene

: 1190958-14-5
4-(2-((tert-butyldimethylsilyl)oxy)pent-4-yn-1-yl)phenol

: 1190958-18-9
C₁₁H₁₀O₂

: 1190958-17-8
1-((tert-butyldimethylsilyl)oxy)-2-(4-oxo-1-(propa-1,2-dien-1-yl)-cyclohexa-2,5-dien-1-yl)ethyl acetate

Guidance literature:: In dichloromethane; 1,1,1,3',3',3'-hexafluoro-propanol; at -17 ℃; for 0.0333333h;
DOI:10.1021/ol902000j

Reference yield:

: 1361118-22-0
1-(4-((tert-butyldimethylsilyl)oxy)phenyl)-5-(trimethylsilyl)pent-4-yn-2-ol

: 1190958-17-8
1-((tert-butyldimethylsilyl)oxy)-2-(4-oxo-1-(propa-1,2-dien-1-yl)-cyclohexa-2,5-dien-1-yl)ethyl acetate

Guidance literature:: Multi-step reaction with 3 steps

1: 1H-imidazole / N,N-dimethyl-formamide / 3 h / 20 °C

2: methanol; potassium carbonate / 12 h / 20 °C

3: 1,1,1,3',3',3'-hexafluoro-propanol / 0.04 h / 0 °C

With 1H-imidazole; methanol; potassium carbonate; In 1,1,1,3',3',3'-hexafluoro-propanol; N,N-dimethyl-formamide;
DOI:10.1021/jo300169k