N-METHYLFULLEROPYRROLIDINE

Base Information

• Chemical Name: N-METHYLFULLEROPYRROLIDINE
• CAS No.: 151872-44-5
• Molecular Formula: C63H7 N
• Molecular Weight: 777.755
• Mol file: 151872-44-5.mol

Synonyms:N-Methylfullerenopyrrolidine;N-Methylfulleropyrrolidine

Chemical Property of N-METHYLFULLEROPYRROLIDINE

Chemical Property:

• PSA: 3.24000
• LogP: 16.17730

Purity/Quality:

98%,99%, ^*data from raw suppliers

N-Methylfulleropyrrolidine 99% (HPLC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Soluble functionalized fullerene. Acts as electron acceptor in mixtures or when linked to π-conjugated molecules and polymers. Used as spectroscopic and redox reference for C60-based molecular heterojunctions.

Technology Process of N-METHYLFULLEROPYRROLIDINE

There total 21 articles about N-METHYLFULLEROPYRROLIDINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

sarcosine (107-97-1,25951-24-0) + tetramethlyammonium chloride (75-57-0) + fullerene-C60 (99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0) + toluene (108-88-3,15644-74-3,16713-13-6) → N-Methylfulleropyrrolidine (151872-44-5) + 1-methyl-2-phenyl[60]fullereno[c]pyrrolidine (174278-70-7)

Guidance literature:

at 105 ℃; for 24h;

DOI:10.1016/j.tetlet.2009.07.097

Reference yield: 64.0%

(+/-)-Diethyl 63-methyl-1,2-(methaniminomethano)-33,50-methano[60]fullerene-61,61-dicarboxylate (267663-62-7) → N-Methylfulleropyrrolidine (151872-44-5)

Guidance literature:

With amalgamated magnesium; In tetrahydrofuran; at 80 ℃; for 72h;

DOI:10.1039/a909704j

Reference yield: 45.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + sarcosine (107-97-1,25951-24-0) + fullerene-C60 (99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0) → N-Methylfulleropyrrolidine (151872-44-5)

Guidance literature:

In toluene; for 2h; Heating;

DOI:10.1021/jo960466t

upstream raw materials:

formaldehyd

sarcosine

fullerene-C₆₀

trimethylamine