(E)-3-(3-chlorophenyl)allyl acetate

Base Information

• Chemical Name: (E)-3-(3-chlorophenyl)allyl acetate
• CAS No.: 115117-78-7
• Molecular Formula: C₁₁H₁₁ClO₂
• Molecular Weight: 210.66
• Mol file: 115117-78-7.mol

Synonyms:(E)-3-(3-chlorophenyl)allyl acetate

Chemical Property of (E)-3-(3-chlorophenyl)allyl acetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-3-(3-chlorophenyl)allyl acetate

There total 3 articles about (E)-3-(3-chlorophenyl)allyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Allyl acetate (591-87-7) + chlorobenzene (108-90-7) → (E)-3-(2-chlorophenyl)allyl acetate (1191300-24-9) + (E)-3-(3-chlorophenyl)allyl acetate (115117-78-7) + (E)-3-(4-chlorophenyl)allyl acetate (170938-14-4)

Guidance literature:

With palladium diacetate; silver carbonate; p-benzoquinone; valeric acid; at 110 ℃; for 48h; stereoselective reaction;

DOI:10.1002/asia.200900558

Reference yield:

1-(3-chlorophenyl)prop-2-en-1-ol (58824-53-6) → (E)-3-(3-chlorophenyl)allyl acetate (115117-78-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 82 percent / 4-dimethylaminopyridine / pyridine / 1 h / Ambient temperature

2: 0.76 g / 2(MeCN)2> / benzene / 1 h / 80 °C

dmap; dichloro bis(acetonitrile) palladium(II); In pyridine; benzene;

Reference yield:

m-Chlorobenzaldehyde (587-04-2) → (E)-3-(3-chlorophenyl)allyl acetate (115117-78-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 56 percent / tetrahydrofuran / 0.67 h / Ambient temperature

2: 82 percent / 4-dimethylaminopyridine / pyridine / 1 h / Ambient temperature

3: 0.76 g / 2(MeCN)2> / benzene / 1 h / 80 °C

dmap; dichloro bis(acetonitrile) palladium(II); In tetrahydrofuran; pyridine; benzene;

upstream raw materials:

1-(3-chlorophenyl)prop-2-en-1-ol

m-Chlorobenzaldehyde

Allyl acetate

chlorobenzene

Downstream raw materials:

(E)-3-(3-chlorophenyl)propenal

(E)-3-(3-chlorophenyl)prop-2-en-1-ol