Methanesulfonic acid (1S,6S)-6-methanesulfonyloxymethyl-cyclohex-3-enylmethyl ester

Base Information

Chemical Name:Methanesulfonic acid (1S,6S)-6-methanesulfonyloxymethyl-cyclohex-3-enylmethyl ester
CAS No.:213918-77-5
Molecular Formula:C₁₀H₁₈O₆S₂
Molecular Weight:298.381
Hs Code.:

Synonyms:Methanesulfonic acid (1S,6S)-6-methanesulfonyloxymethyl-cyclohex-3-enylmethyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methanesulfonic acid (1S,6S)-6-methanesulfonyloxymethyl-cyclohex-3-enylmethyl ester

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Technology Process of Methanesulfonic acid (1S,6S)-6-methanesulfonyloxymethyl-cyclohex-3-enylmethyl ester

There total 1 articles about Methanesulfonic acid (1S,6S)-6-methanesulfonyloxymethyl-cyclohex-3-enylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 15679-27-3
(4S,5S)-4,5-bis(hydroxymethyl)cyclohexene

: 124-63-0
methanesulfonyl chloride

: 213918-77-5
Methanesulfonic acid (1S,6S)-6-methanesulfonyloxymethyl-cyclohex-3-enylmethyl ester

Guidance literature:: With pyridine; at 0 ℃; for 18h;
DOI:10.1016/j.bmcl.2009.10.121

Reference yield: 98.0%

: 213918-77-5
Methanesulfonic acid (1S,6S)-6-methanesulfonyloxymethyl-cyclohex-3-enylmethyl ester

: 213918-78-6
(S,S)-4,5-dimethylcyclohexene

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; at 40 ℃; for 2h;
DOI:10.1016/j.bmcl.2009.10.121

Reference yield:

: 213918-77-5
Methanesulfonic acid (1S,6S)-6-methanesulfonyloxymethyl-cyclohex-3-enylmethyl ester

: 213918-76-4
(4S,5S)-2-hydroxy-4,5-dimethyl-cyclohex-2-enone

Guidance literature:: Multi-step reaction with 3 steps

1: LiAlH₄ / diethyl ether; tetrahydrofuran / 15 h / Heating

2: 1.) OsO₄, N-methylmorpholine-N-oxide, 2.) aq. sodium sulfite / 1.) t-BuOH, THF, 17 h, 2.) t-BuOH, THF

3: 90 percent / trifluoroacetic anhydride, DMSO / CH₂Cl₂ / 1.5 h / -60 °C

With osmium(VIII) oxide; lithium aluminium tetrahydride; dimethyl sulfoxide; 4-methylmorpholine N-oxide; trifluoroacetic anhydride; sodium sulfite; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1016/S0957-4166(98)00227-4