2,9-dicyclohexyl-5,12-dinitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone

Base Information

• Chemical Name: 2,9-dicyclohexyl-5,12-dinitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone
• CAS No.: 1257079-47-2
• Molecular Formula: C₃₆H₂₈N₄O₈
• Molecular Weight: 644.64
• Mol file: 1257079-47-2.mol

Synonyms:2,9-dicyclohexyl-5,12-dinitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone

Chemical Property of 2,9-dicyclohexyl-5,12-dinitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,9-dicyclohexyl-5,12-dinitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone

There total 7 articles about 2,9-dicyclohexyl-5,12-dinitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

2,9-dicyclohexyl-5-nitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone (1257079-45-0) → 2,9-dicyclohexyl-5,12-dinitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone (1257079-47-2) + 1,6-dinitro-N,N’-dicyclohexylperylene-3,4:9,10-bis(dicarboximide)

Guidance literature:

With ammonium cerium (IV) nitrate; nitric acid; In dichloromethane; at 20 ℃; for 48h; Inert atmosphere;

DOI:10.1021/acs.joc.8b02023

Reference yield: 21.0%

N,N'-bis(cyclohexyl)perylene-3,4,9,10-tetracarboxylic acid diimide (41572-86-5) → 2,9-dicyclohexyl-5,12-dinitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone (1257079-47-2) + 1,6-dinitro-N,N’-dicyclohexylperylene-3,4:9,10-bis(dicarboximide)

Guidance literature:

With ammonium cerium (IV) nitrate; nitric acid; In dichloromethane; at 25 ℃; for 48h; Inert atmosphere;

DOI:10.1007/s12039-017-1221-6

Reference yield:

2,9-dicyclohexyl-5-nitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone (1257079-45-0) → 2,9-dicyclohexyl-5,12-dinitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone (1257079-47-2)

Guidance literature:

With ammonium cerium (IV) nitrate; nitric acid; In dichloromethane; at 25 ℃; for 48h; Inert atmosphere;

DOI:10.1016/j.tetlet.2010.09.029

upstream raw materials:

2,9-dicyclohexyl-5-nitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone

N,N'-bis(cyclohexyl)perylene-3,4,9,10-tetracarboxylic acid diimide

cyclohexylamine

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

Downstream raw materials:

1,7-diaminoperylene bisimide