NiN₄C₂₀H₆(C₆H₅)4C₂H₂NCH₃

Base Information

• Chemical Name: NiN₄C₂₀H₆(C₆H₅)4C₂H₂NCH₃
• CAS No.: 202463-09-0
• Molecular Formula: C₄₇H₃₁N₅Ni
• Molecular Weight: 724.487
• Mol file: 202463-09-0.mol

Synonyms:NiN₄C₂₀H₆(C₆H₅)4C₂H₂NCH₃

Chemical Property of NiN₄C₂₀H₆(C₆H₅)4C₂H₂NCH₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of NiN₄C₂₀H₆(C₆H₅)4C₂H₂NCH₃

There total 1 articles about NiN₄C₂₀H₆(C₆H₅)4C₂H₂NCH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

sarcosine (107-97-1,25951-24-0) + (β-formyl-meso-tetraphenylporphyrinato)nickel(II) (42565-85-5) → NiN4C20H6(C6H5)4C2H2NCH3 (202463-09-0)

Guidance literature:

With potassium carbonate; In toluene; toluene soln. nickel(II) 2-formyl-5,10,15,20-tetraphenylporphyrin, N-methyl glycine and K2CO3 was refluxed for 24 h under N2 atm.; react. mixt. was cooled to room temp. and filtered, org. layer was washed with water, dried over Na2SO4, concd. and purified by column chromy. (silica, CH2Cl2-p.e. 3:7);

DOI:10.1039/b108783p

Reference yield: 100.0%

NiN4C20H6(C6H5)4C2H2NCH3 (202463-09-0) + dimethyl acetylenedicarboxylate (762-42-5) → C59H43N5NiO8 (1443978-52-6)

Guidance literature:

In toluene; for 1h; Reflux;

DOI:10.1021/jo400948s

Reference yield: 70.0%

NiN4C20H6(C6H5)4C2H2NCH3 (202463-09-0) → C47H29N5NiO2 (1259580-75-0)

Guidance literature:

NiN₄C₂₀H₆(C₆H₅)4C₂H₂NCH₃; With 5,15,10,20-tetraphenylporphyrin; In 1,2-dichloro-benzene; at 20 ℃; for 1.5h; Irradiation;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In 1,2-dichloro-benzene; for 0.5h; Reflux;

DOI:10.1021/ol102691s

upstream raw materials:

sarcosine

(β-formyl-meso-tetraphenylporphyrinato)nickel(II)

Downstream raw materials:

C₄₇H₂₉N₅NiO₂

C₄₇H₃₁N₅NiO₂

C₄₇H₃₁N₅NiO₃

C₄₆H₃₁N₅NiO