trans-undeca-1,3-diene

Base Information

• Chemical Name: trans-undeca-1,3-diene
• CAS No.: 79309-74-3
• Molecular Formula: C₁₁H₂₀
• Molecular Weight: 152.28
• Mol file: 79309-74-3.mol

Synonyms:trans-undeca-1,3-diene

Chemical Property of trans-undeca-1,3-diene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-undeca-1,3-diene

There total 1 articles about trans-undeca-1,3-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

(1-octyl-prop-2-ynyloxymethyl)-benzene (443306-62-5) → undeca-1,3-diene (79309-73-2,79309-74-3,54826-10-7) + benzaldehyde (100-52-7)

Guidance literature:

With LoOTf; TpRu(PPh₃)(CH₃CN)2PF₆; In 1,2-dichloro-ethane; benzene; at 80 ℃; for 15h; Further Variations:; Catalysts; Solvents; Reagents; times; Product distribution;

DOI:10.1021/jo049514x

Reference yield: 82.0%

cyclohex-1-en-1-yl trifluoromethane sulfonate (28075-50-5) + trans-undeca-1,3-diene (79309-74-3) → C17H30

Guidance literature:

With bis(1,5-cyclooctadiene)nickel⁽⁰⁾; C₃₅H₄₆NP; cesium fluoride; In tetrahydrofuran; di-isopropyl ether; at 0 ℃; for 48h; regioselective reaction; Inert atmosphere; Sealed tube; Glovebox;

DOI:10.1021/jacs.1c00142

Reference yield: 58.0%

phthalimide (136918-14-4,85-41-6) + (3-bromo-3-methyl-n-butyl)benzene (52017-21-7) + undeca-1,3-diene (79309-73-2,79309-74-3,54826-10-7) → (E)-2-(3,3-dimethyl-1-phenyltetradec-5-en-7-yl)isoindoline-1,3-dione

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium acetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; In tetrahydrofuran; N,N-dimethyl acetamide; at 20 ℃; for 48h; Schlenk technique; Irradiation; Inert atmosphere;

DOI:10.1021/jacs.0c03239

upstream raw materials:

(1-octyl-prop-2-ynyloxymethyl)-benzene

Downstream raw materials:

1-heptyl-3-(trimethylsilyl)benzene

((1R,5R,6R)-5-Heptyl-6-nitro-cyclohex-3-enesulfonyl)-benzene