trans-Ru(CO)3(N-(diphenylphosphinomethyl)morpholine)2

Base Information

• Chemical Name: trans-Ru(CO)3(N-(diphenylphosphinomethyl)morpholine)2
• CAS No.: 414860-08-5
• Molecular Formula: C₃₇H₄₀N₂O₅P₂Ru
• Molecular Weight: 755.753
• Mol file: 414860-08-5.mol

Synonyms:trans-Ru(CO)3(N-(diphenylphosphinomethyl)morpholine)2

Chemical Property of trans-Ru(CO)3(N-(diphenylphosphinomethyl)morpholine)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-Ru(CO)3(N-(diphenylphosphinomethyl)morpholine)2

There total 1 articles about trans-Ru(CO)3(N-(diphenylphosphinomethyl)morpholine)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + N-(Diphenylphosphinomethyl)morpholine (301662-60-2) → trans-Ru(CO)3(N-(diphenylphosphinomethyl)morpholine)2 (414860-08-5)

Guidance literature:

With Na; H₂SO₄; In ethanol; ammonia; NH3 (liquid); 6 equiv. of Na was added to liq. NH3 soln. of Ru3(CO)12 at -50 °C, stirring for 2 h, NH3 was evapd., drying in vac., EtOH and 1.5 equiv. of 98 % H2SO4 was added, stirring for 2 min, 6 equiv. of ligand was added, 70 °C for 2 h; soln. was cooled to room temp., ppt. was filtered off, solid was dissolved in CH2Cl2, soln. was filtered, concd., MeOH was added, keeping in refrigetaror overnight, ppt. was filtered off, dried in vac., elem. anal.;

DOI:10.1039/b108287f

Reference yield: 95.0%

dichloromethane (75-09-2) + trans-Ru(CO)3(N-(diphenylphosphinomethyl)morpholine)2 (414860-08-5) → trans,cis-Ru(CO)2(μ-(N-(diphenylphosphinomethyl)morpholine))2Cl2*0.5CH2Cl2

Guidance literature:

In dichloromethane; CH2Cl2 soln. was allowed to stand for a week; MeOH was added at -20 °C, elem. anal.;

DOI:10.1039/b108287f

Reference yield: 83.0%

trans-Ru(CO)3(N-(diphenylphosphinomethyl)morpholine)2 (414860-08-5) + mercury(II) iodide → Ru(CO)3(μ-(N-(diphenylphosphinomethyl)morpholine))2HgI2 (414860-10-9)

Guidance literature:

In dichloromethane; HgI2 was added to CH2Cl2-soln. of Ru-complex, stirring at room temp. for2 h; soln. was filtered, concd., n-hexane was added, elem. anal.;

DOI:10.1039/b108287f

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

N-(Diphenylphosphinomethyl)morpholine

Downstream raw materials:

trans,cis-Ru(CO)2(μ-(N-(diphenylphosphinomethyl)morpholine))2Cl2*CH2Cl2

Ru(CO)3(μ-(N-(diphenylphosphinomethyl)morpholine))2CdI2*Et2O

Ru(CO)3(μ-(N-(diphenylphosphinomethyl)morpholine))2HgI2