(2S,3S,4E)-1-[(4-methylphenyl)sulfonyl]-4-[1-(benzyldimethylsilyl)ethylidene]-2-methoxycarbonyl-3-pyrrolidineacetaldehyde

Base Information

Chemical Name:(2S,3S,4E)-1-[(4-methylphenyl)sulfonyl]-4-[1-(benzyldimethylsilyl)ethylidene]-2-methoxycarbonyl-3-pyrrolidineacetaldehyde
CAS No.:1259286-19-5
Molecular Formula:C₂₆H₃₃NO₅SSi
Molecular Weight:499.703
Hs Code.:

Synonyms:(2S,3S,4E)-1-[(4-methylphenyl)sulfonyl]-4-[1-(benzyldimethylsilyl)ethylidene]-2-methoxycarbonyl-3-pyrrolidineacetaldehyde

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Chemical Property of (2S,3S,4E)-1-[(4-methylphenyl)sulfonyl]-4-[1-(benzyldimethylsilyl)ethylidene]-2-methoxycarbonyl-3-pyrrolidineacetaldehyde

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Technology Process of (2S,3S,4E)-1-[(4-methylphenyl)sulfonyl]-4-[1-(benzyldimethylsilyl)ethylidene]-2-methoxycarbonyl-3-pyrrolidineacetaldehyde

There total 7 articles about (2S,3S,4E)-1-[(4-methylphenyl)sulfonyl]-4-[1-(benzyldimethylsilyl)ethylidene]-2-methoxycarbonyl-3-pyrrolidineacetaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 201230-82-2
carbon monoxide

: C₁₆H₁₉NO₄S

: 1631-70-5
benzyldimethylsilane

: C₂₆H₃₃NO₅SSi

: 1259286-19-5
(2S,3S,4E)-1-[(4-methylphenyl)sulfonyl]-4-[1-(benzyldimethylsilyl)ethylidene]-2-methoxycarbonyl-3-pyrrolidineacetaldehyde

Guidance literature:: With (acetylacetonato)dicarbonylrhodium (l); In toluene; at 120 ℃; for 12h; under 25858.1 - 31029.7 Torr; optical yield given as %de; diastereoselective reaction; Autoclave;
DOI:10.1021/jo101790z

Reference yield:

: 201230-82-2
carbon monoxide

: C₁₆H₁₉NO₄S

: 1631-70-5
benzyldimethylsilane

: C₂₅H₃₃NO₄SSi

: C₂₆H₃₃NO₅SSi

: 1259286-19-5
(2S,3S,4E)-1-[(4-methylphenyl)sulfonyl]-4-[1-(benzyldimethylsilyl)ethylidene]-2-methoxycarbonyl-3-pyrrolidineacetaldehyde

Guidance literature:: With (acetylacetonato)dicarbonylrhodium (l); In toluene; at 150 ℃; for 12h; under 7757.43 Torr; optical yield given as %de; diastereoselective reaction; Autoclave;
DOI:10.1021/jo101790z

Reference yield:

: 201230-82-2
carbon monoxide

: C₁₆H₁₉NO₄S

: 1631-70-5
benzyldimethylsilane

: C₂₅H₃₃NO₄SSi

: C₂₆H₃₃NO₅SSi

: C₂₆H₃₃NO₅SSi

: 1259286-19-5
(2S,3S,4E)-1-[(4-methylphenyl)sulfonyl]-4-[1-(benzyldimethylsilyl)ethylidene]-2-methoxycarbonyl-3-pyrrolidineacetaldehyde

Guidance literature:: With (acetylacetonato)dicarbonylrhodium (l); In toluene; at 70 ℃; for 12h; under 36201.3 Torr; optical yield given as %de; diastereoselective reaction; Autoclave;
DOI:10.1021/jo101790z