diphenyl 2,2'-dihydroxy-[1,1'-binaphthalene]-3,3'-dicarboxylate

Base Information

• Chemical Name: diphenyl 2,2'-dihydroxy-[1,1'-binaphthalene]-3,3'-dicarboxylate
• CAS No.: 170889-47-1
• Molecular Formula: C₃₄H₂₂O₆
• Molecular Weight: 526.545
• Mol file: 170889-47-1.mol

Synonyms:diphenyl 2,2'-dihydroxy-[1,1'-binaphthalene]-3,3'-dicarboxylate

Chemical Property of diphenyl 2,2'-dihydroxy-[1,1'-binaphthalene]-3,3'-dicarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of diphenyl 2,2'-dihydroxy-[1,1'-binaphthalene]-3,3'-dicarboxylate

There total 14 articles about diphenyl 2,2'-dihydroxy-[1,1'-binaphthalene]-3,3'-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

6-Methoxy-2-naphthol (5111-66-0) + phenyl 2-hydroxy-3-naphthoate (7260-11-9) → phenyl 2,2'-dihydroxy-6'-methoxy-1,1'-binaphthalene-3-carboxylate + diphenyl 2,2'-dihydroxy-[1,1'-binaphthalene]-3,3'-dicarboxylate (170889-47-1)

Guidance literature:

With oxygen; (S,S)-2,2'-isopropylidenebis(4-phenyl-2-oxazoline); copper(l) chloride; In tetrahydrofuran; at 20 ℃; for 3h;

DOI:10.1016/j.tetlet.2005.06.098

Reference yield: 76.0%

2-benzyloxy-6-hydroxynaphthalene (2041-17-0) + phenyl 2-hydroxy-3-naphthoate (7260-11-9) → phenyl 2,2'-dihydroxy-6'-benzoxy-1,1'-binaphthalene-3-carboxylate + diphenyl 2,2'-dihydroxy-[1,1'-binaphthalene]-3,3'-dicarboxylate (170889-47-1)

Guidance literature:

With oxygen; (S,S)-2,2'-isopropylidenebis(4-phenyl-2-oxazoline); copper(l) chloride; In tetrahydrofuran; at 20 ℃; for 3h;

DOI:10.1016/j.tetlet.2005.06.098

Reference yield: 75.0%

phenyl 2-hydroxy-3-naphthoate (7260-11-9) → diphenyl 2,2'-dihydroxy-[1,1'-binaphthalene]-3,3'-dicarboxylate (170889-47-1)

Guidance literature:

With oxygen; In toluene; at 20 ℃; for 12h; Irradiation; Green chemistry;

DOI:10.1002/cctc.201701470

upstream raw materials:

6-Methoxy-2-naphthol

phenyl 2-hydroxy-3-naphthoate

7-methoxy-2-naphthol

3-methoxy-2-naphthol

Refernces

• 1、 Zhao, Xiao-Jing,Li, Zi-Hao,Ding, Tong-Mei,Tian, Jin-Miao,Tu, Yong-Qiang,Wang, Ai-Fang,Xie, Yu-Yang. "Enantioselective Synthesis of 3,3′-Disubstituted 2-Amino-2′-hydroxy-1,1′-binaphthyls by Copper-Catalyzed Aerobic Oxidative Cross-Coupling". supporting information. p. 7061 - 7065. Retrieved 2021/02/27.
• 2、 Yan, Pei,Sugiyama, Yukihiro,Takahashi, Yusuke,Kinemuchi, Haruki,Temma, Tomohisa,Habaue, Shigeki. "Lewis acid-assisted oxidative cross-coupling of 2-naphthol derivatives with copper catalysts". . p. 4325 - 4331. Retrieved 2008/09/20.