[2,6-dioxo-4-(4-methoxyphenyl)cyclohexyl]phenyliodonium inner salt

Base Information

• Chemical Name: [2,6-dioxo-4-(4-methoxyphenyl)cyclohexyl]phenyliodonium inner salt
• CAS No.: 1415261-30-1
• Molecular Formula: C₁₉H₁₇IO₃
• Molecular Weight: 420.247
• Mol file: 1415261-30-1.mol

Synonyms:[2,6-dioxo-4-(4-methoxyphenyl)cyclohexyl]phenyliodonium inner salt

Chemical Property of [2,6-dioxo-4-(4-methoxyphenyl)cyclohexyl]phenyliodonium inner salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [2,6-dioxo-4-(4-methoxyphenyl)cyclohexyl]phenyliodonium inner salt

There total 1 articles about [2,6-dioxo-4-(4-methoxyphenyl)cyclohexyl]phenyliodonium inner salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

[bis(acetoxy)iodo]benzene (3240-34-4) + 5-(4-methoxyphenyl)-1,3-cyclohexanedione (1774-12-5) → [2,6-dioxo-4-(4-methoxyphenyl)cyclohexyl]phenyliodonium inner salt (1415261-30-1)

Guidance literature:

In dichloromethane; at 20 ℃; for 2h;

DOI:10.1016/j.tet.2012.12.006

Reference yield: 79.0%

diphenylacetic acid chloride (1871-76-7) + [2,6-dioxo-4-(4-methoxyphenyl)cyclohexyl]phenyliodonium inner salt (1415261-30-1) → 2-chloro-5-(p-methoxyphenyl)-3-oxocyclohex-1-enyl 2,2-diphenylethanoate (1415261-49-2)

Guidance literature:

In dichloromethane; at 20 ℃; for 12h;

DOI:10.1021/jo3020787

Reference yield: 70.0%

N-methoxybenzamide (2446-51-7) + [2,6-dioxo-4-(4-methoxyphenyl)cyclohexyl]phenyliodonium inner salt (1415261-30-1) → 5-methoxy-3-(4-methoxyphenyl)-3,4-dihydrophenanthridine-1,6(2H,5H)-dione

Guidance literature:

With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; cesium acetate; In acetone; at 85 ℃; for 12h; Inert atmosphere;

DOI:10.1039/d0cc06038k

upstream raw materials:

[bis(acetoxy)iodo]benzene

5-(4-methoxyphenyl)-1,3-cyclohexanedione

Downstream raw materials:

6-(4-methoxyphenyl)-2-phenyl-2,3,6,7-tetrahydrobenzofuran-4(5H)-one

2,2-diphenyl-6-(p-methoxyphenyl)-6,7-dihydrobenzofuran-3,4(2H,5H)-dione

C₂₇H₂₂O₄

2-chloro-5-(p-methoxyphenyl)-3-oxocyclohex-1-enyl 2,2-diphenylethanoate