N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene

Base Information

• Chemical Name: N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene
• CAS No.: 1161783-13-6
• Molecular Formula: C₁₉H₁₆N₄O₃
• Molecular Weight: 348.361
• Mol file: 1161783-13-6.mol

Synonyms:N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene

Chemical Property of N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene

There total 1 articles about N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

chloroglyoxime (4732-58-5) + 2-[(4-aminonaphthalen-1-ylimino)methyl]phenol (1161783-12-5) → N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene (1161783-13-6)

Guidance literature:

With sodium hydrogencarbonate; In ethanol; water; at 60 - 70 ℃; for 5h;

DOI:10.1134/S1070363208050186

Reference yield: 55.0%

N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene (1161783-13-6) + copper(II) acetate monohydrate (6046-93-1) → [Cu(N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene(-1H))2]

Guidance literature:

With NaOH; In ethanol; water; soln. of metal salt in H2O added to soln. of ligand in EtOH; pH adjustedto 4.5-5.0 (0.1 N NaOH); mixt. kept on water bath at 25°C for 2 h; ppt. filtered off; washed (H2O, Et2O, cold EtOH); dried (vac., 70°C); elem. anal.;

DOI:10.1134/S1070363208050186

upstream raw materials:

chloroglyoxime

2-[(4-aminonaphthalen-1-ylimino)methyl]phenol