4732-58-5

Upstream product

• 5653-21-4 metazonic acid 
• 302-17-0 chloral hydrate 
• 4732-58-5 (E,E)-monochloroglyoxime 
• 75-87-6 chloral 
• 17019-15-7 (1Z,2E)-N-hydroxy-2-(hydroxyimino)-acetimidoyl chloride 

Downstream Products

• 4474-18-4 cyanoformic acid chloride oxime 
• 87259-62-9 s-trans N-(phenyl)aminoglyoxime 
• 1161783-13-6 N-(glyoxyldioxime)-N'-(2-hydroxybenzylidene)-1,4-diaminonaphthalene 
• 1376083-48-5 Co(II)(α-benzyldioxime-2H)2(monochloroglyoxime-2H)(BF)2 
• 2038-44-0 dichloroglyoxime 
• 1246657-96-4 N,N'-[2,2'-{ethane-1,2-di-yl-bis(oxy)bis(2,1-phenylene)}bis(N'-hydroxy)-2-(hydroxyimino)acetamidamide] 
• 1228601-12-4 N,N'-[4,4'-{ethane-1,2-di-yl-bis(oxy)bis(4,1-phenylene)}bis(N'-hydroxy)-2-(hydroxyimino)acetamidamide] 
• 1312668-77-1 anti-N-(4-aminophenyl)aza-15-crown-5 glyoxime 
• 1402350-24-6 C₄₁H₅₃N₇O₂ 
• 89324-20-9 5-Aethinyl-3-formyl-isoxazol-oxim 

Relevant academic research and scientific papers

On the Reaction of Chloroglyoximes with Aryl Isocyanates

Reaction of chloroglyoxime 1 with aryl isocyanates yielded monocarbamates 3, and chlorooxime functional group was unchanged.The 1,3-cycloaddition of nitrile N-oxides generated from 3 to methyl methacrylate gave isoxazole derivatives 5.Compounds 5 were als

Methods for the Stereoselective Cis Cyanohydroxylation and Carboxyhydroxylation of Olefins

Two valuable reagents for the cis-specific vicinal cyanohydroxylation and carboxyhydroxylation of olefins are described.The cyanohydroxylation process is based on the decarboxylative ring opening of 3-carboxyisoxazolines prepared by the cycloaddition reaction of carbethoxyformonitrile oxide with various alkenes.Fragmentation of the isoxazolines prepared from cis- and trans-2-butene has been found to occur without any crossover in stereochemistry.The carboxyhydroxylation process begins with the dipolar cycloaddition reaction of the nitrile oxide derived from thetetrahydropyranyl ether derivative of 2-nitroethanol.Deprotection, hydrogenation, and oxitative cleavage of the derived dihydroxy ketone yield the stereochemcally pure β-hydroxy carboxylic acid.