(6R)-N,N-dibenzyl-2,2,10,10,11,11-hexamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecan-6-amine

Base Information

Chemical Name:(6R)-N,N-dibenzyl-2,2,10,10,11,11-hexamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecan-6-amine
CAS No.:1397262-10-0
Molecular Formula:C₄₀H₅₅NO₂Si₂
Molecular Weight:638.053
Hs Code.:

Synonyms:(6R)-N,N-dibenzyl-2,2,10,10,11,11-hexamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecan-6-amine

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Chemical Property of (6R)-N,N-dibenzyl-2,2,10,10,11,11-hexamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecan-6-amine

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Technology Process of (6R)-N,N-dibenzyl-2,2,10,10,11,11-hexamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecan-6-amine

There total 1 articles about (6R)-N,N-dibenzyl-2,2,10,10,11,11-hexamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecan-6-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 616890-44-9
(2R)-4-{[tert-butyl(dimethyl)silyl]oxy}-2-(dibenzylamino)butan-1-ol

: 1397262-10-0
(6R)-N,N-dibenzyl-2,2,10,10,11,11-hexamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecan-6-amine

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 15h;
DOI:10.1021/jm3008008

Reference yield: 95.0%

: 1397262-10-0
(6R)-N,N-dibenzyl-2,2,10,10,11,11-hexamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecan-6-amine

: 1397262-11-1
(3R)-4-{[tert-butyl(diphenyl)silyl]oxy}-3-(dibenzylamino)butan-1-ol

Guidance literature:: (6R)-N,N-dibenzyl-2,2,10,10,11,11-hexamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecan-6-amine; With hydrogenchloride; In 1,4-dioxane; water; at 20 ℃; for 1h;

With sodium hydrogencarbonate; In 1,4-dioxane; water; ethyl acetate;
DOI:10.1021/jm3008008

Reference yield:

: 1397262-10-0
(6R)-N,N-dibenzyl-2,2,10,10,11,11-hexamethyl-3,3-diphenyl-4,9-dioxa-3,10-disiladodecan-6-amine

: 1187575-49-0
N-[(2R)-1-{[tert-butyl(diphenyl)silyl]oxy}-4-hydroxybutan-2-yl]hydrazinecarbothioamide

Guidance literature:: Multi-step reaction with 4 steps

1: hydrogenchloride / 1,4-dioxane; water / 1 h / 20 °C

2: 10% Pd/C; ammonium formate / ethanol / 4 h / 20 °C / Reflux

3: sodium hydrogencarbonate / dichloromethane; water / 0.5 h / 0 - 20 °C

4: hydrazine hydrate / isopropyl alcohol / 2 h / 20 °C

With hydrogenchloride; 10% Pd/C; ammonium formate; sodium hydrogencarbonate; hydrazine hydrate; In 1,4-dioxane; ethanol; dichloromethane; water; isopropyl alcohol;
DOI:10.1021/jm3008008