menthyl allyl carbonate

Base Information

• Chemical Name: menthyl allyl carbonate
• CAS No.: 76648-56-1
• Molecular Formula: C₁₄H₂₄O₃
• Molecular Weight: 240.343
• Mol file: 76648-56-1.mol

Synonyms:menthyl allyl carbonate

Chemical Property of menthyl allyl carbonate

Chemical Property:

Purity/Quality:

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Technology Process of menthyl allyl carbonate

There total 1 articles about menthyl allyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(-)-menthol (2216-51-5) + Allyl chloroformate (2937-50-0) → menthyl allyl carbonate (76648-56-1)

Guidance literature:

With pyridine; at 0 - 20 ℃;

DOI:10.1021/ol202270g

Reference yield: 100.0%

menthyl allyl carbonate (76648-56-1) + 2-propanethiol (75-33-2) → allylisopropyl sulfide (50996-72-0) + carbon dioxide (124-38-9,18923-20-1) + (-)-menthol (2216-51-5)

Guidance literature:

With Roussin's red salt ester; tetrabutylammomium bromide; potassium hydride; In tetrahydrofuran; ethanol; at 40 ℃; for 14h;

DOI:10.1021/ol202270g

Reference yield: 100.0%

menthyl allyl carbonate (76648-56-1) → (-)-menthol (2216-51-5)

Guidance literature:

With diethylamine; palladium diacetate; trisodium tris(3-sulfophenyl)phosphine; In water; for 0.5h; Ambient temperature;

DOI:10.1016/S0040-4020(01)80771-7

upstream raw materials:

(-)-menthol

Allyl chloroformate

Downstream raw materials:

(-)-menthol

allylisopropyl sulfide

carbon dioxide

Refernces