dimethylphenylphosphine borane

Base Information

• Chemical Name: dimethylphenylphosphine borane
• CAS No.: 35512-87-9
• Molecular Formula: C₈H₁₄BP
• Molecular Weight: 151.984
• Mol file: 35512-87-9.mol

Synonyms:dimethylphenylphosphine borane

Chemical Property of dimethylphenylphosphine borane

Chemical Property:

• Refractive Index: 1.5490-1.5530
• Boiling Point: 78°C/0.03mmHg(lit.)

Purity/Quality:

97% ^*data from raw suppliers

Dimethylphenylphosphine Borane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of dimethylphenylphosphine borane

There total 27 articles about dimethylphenylphosphine borane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

dimethylsulfide borane complex (13292-87-0) + Dimethyl(phenyl)phosphine (672-66-2) → dimethylphenylphosphine borane (35512-87-9)

Guidance literature:

In dichloromethane; at 20 ℃; for 15h; Inert atmosphere;

DOI:10.1021/acs.joc.1c02729

Reference yield: 89.0%

syn-[(η5-C5Me5)IrB18H20] + Dimethyl(phenyl)phosphine (672-66-2) → 11-(dimethylphenylphosphine)-9-pentahapto-pentamethylcyclopentanedienyl-9-hydrido-nido-9-iridaundecaborano-(7,8:5',6')-nido-decaborane + dimethylphenylphosphine borane (35512-87-9)

Guidance literature:

In dichloromethane; PMe2Ph was added to soln. ((η5-C5Me5)Ir-syn-B18H20) in CH2Cl2, 24 h; solvent was removed in vacuo, TLC (silica, CH2Cl2/hexane 50/50);

DOI:10.1039/b404322g

Reference yield: 88.0%

methylmagnesium bromide (75-16-1) + Dichlorophenylphosphine (644-97-3) → dimethylphenylphosphine borane (35512-87-9)

Guidance literature:

methylmagnesium bromide; Dichlorophenylphosphine; In tetrahydrofuran; diethyl ether; at 0 - 20 ℃; for 16h; Inert atmosphere;

With dimethylsulfide borane complex; In tetrahydrofuran; diethyl ether; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ol303253h

upstream raw materials:

dimethylphenylphosphine sulfide

trimethylamine-borane

Dimethyl(phenyl)phosphine

cis-bis(dimethylphenylphosphine)dichloropalladium

Downstream raw materials:

(R)-hydroxymethyl(methyl)phenylphosphine-borane

(R)-(+)-[(O-methyl)methylphenylphosphinite]borane

(C₆H₅P(BH₃)(CH₃)CH₂)2

(S_P,S_P)-1,2-bis[(methyl)(phenyl)phosphino-P-borane]ethane