(-)-menthol-MTM

Base Information

• Chemical Name: (-)-menthol-MTM
• CAS No.: 19245-61-5
• Molecular Formula: C₁₂H₂₄OS
• Molecular Weight: 216.388
• Mol file: 19245-61-5.mol

Synonyms:(-)-menthol-MTM

Chemical Property of (-)-menthol-MTM

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (-)-menthol-MTM

There total 2 articles about (-)-menthol-MTM which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

chloro-methylsulfanyl-methane (2373-51-5) + (-)-menthol (2216-51-5) → (-)-menthol-MTM (19245-61-5)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In chloroform; for 8h; Heating;

DOI:10.1080/00397910701471337

Reference yield: 36.0%

(-)-menthol (2216-51-5) + dimethyl sulfoxide (67-68-5,8070-53-9) → (-)-menthol-MTM (19245-61-5)

Guidance literature:

With acetic anhydride; acetic acid; at 23 ℃; for 48h; Inert atmosphere;

DOI:10.1021/ja906514s

Reference yield: 69.0%

benzaldehyde (100-52-7) + (-)-menthol-MTM (19245-61-5) → C19H30O2S

Guidance literature:

(-)-menthol-MTM; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 0 ℃;

benzaldehyde; In tetrahydrofuran; hexane; at -78 - -25 ℃; for 8h; Further stages.;

DOI:10.1080/00397910701471337

upstream raw materials:

(-)-menthol

dimethyl sulfoxide

chloro-methylsulfanyl-methane

Downstream raw materials:

(3-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyloxy)prop-1-ynyl)benzene