Cyclopropanecarboxylic acid, 2-(hydroxymethyl)-, ethyl ester, (1S-trans)- (9CI)

Base Information

Chemical Name:Cyclopropanecarboxylic acid, 2-(hydroxymethyl)-, ethyl ester, (1S-trans)- (9CI)
CAS No.:109716-55-4
Molecular Formula:C7H12 O3
Molecular Weight:144.17
Hs Code.:
Mol file:109716-55-4.mol

Synonyms:Cyclopropanecarboxylicacid, 2-(hydroxymethyl)-, ethyl ester, (1S-trans)- (9CI)

Suppliers and Price of Cyclopropanecarboxylic acid, 2-(hydroxymethyl)-, ethyl ester, (1S-trans)- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 2 raw suppliers

Chemical Property of Cyclopropanecarboxylic acid, 2-(hydroxymethyl)-, ethyl ester, (1S-trans)- (9CI)

Chemical Property:

Boiling Point:205.9±13.0 °C(Predicted)
PKA:15.10±0.10(Predicted)
PSA：46.53000
Density:1.144±0.06 g/cm3(Predicted)
LogP:0.17790

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Cyclopropanecarboxylic acid, 2-(hydroxymethyl)-, ethyl ester, (1S-trans)- (9CI)

There total 9 articles about Cyclopropanecarboxylic acid, 2-(hydroxymethyl)-, ethyl ester, (1S-trans)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 13949-93-4
(+/-)-ethyl trans-2-formyl-1-cyclopropanecarboxylate

: 15224-11-0,40427-14-3,77183-93-8,84673-56-3,109716-55-4
ethyl (1S*,2S*)-2-(hydroxymethyl)cyclopropane-1-carboxylate

Guidance literature:: With sodium tetrahydroborate; In methanol; at 0 ℃; for 1h; Inert atmosphere;
DOI:10.1039/c7ob01721a

Reference yield: 87.0%

: 31420-66-3,71666-05-2,149520-04-7
(±)-trans-2-(ethoxycarbonyl)cyclopropanecarboxylic acid

: 15224-11-0,40427-14-3,77183-93-8,84673-56-3,109716-55-4
ethyl (1S*,2S*)-2-(hydroxymethyl)cyclopropane-1-carboxylate

Guidance literature:: With borane-THF; at -10 - 20 ℃;

Reference yield: 83.0%

: 623-73-4
diazoacetic acid ethyl ester

: 107-18-6
allyl alcohol

: 15224-07-4
(Allyloxy)essigsaeure-ethylester

: 15224-11-0,40427-14-3,77183-93-8,84673-56-3,109716-55-4
ethyl (1S*,2S*)-2-(hydroxymethyl)cyclopropane-1-carboxylate

: 82442-65-7
(+/-)-cis-3-oxabicyclo<3.1.0>hexan-2-one

Guidance literature:: With RuCl(p-cymene)*(tosylamide-pyridine); at 60 ℃; for 4h; Product distribution; var. ruthenium complexes, temp.; var. alcohol;
DOI:10.1016/S0040-4039(98)80020-8