ethylthio 2-O-benzoyl-4-O-benzyl-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside

Base Information

• Chemical Name: ethylthio 2-O-benzoyl-4-O-benzyl-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside
• CAS No.: 460741-89-3
• Molecular Formula: C₂₈H₄₀O₆SSi
• Molecular Weight: 532.774

Synonyms:ethylthio 2-O-benzoyl-4-O-benzyl-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside

Chemical Property of ethylthio 2-O-benzoyl-4-O-benzyl-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethylthio 2-O-benzoyl-4-O-benzyl-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside

There total 1 articles about ethylthio 2-O-benzoyl-4-O-benzyl-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

ethyl 2-O-benzoyl-4,6-O-benzylidene-3-O-(tert-butyldimethylsilyl)-1-thio-β-D-glucopyranoside (460741-88-2) → ethylthio 2-O-benzoyl-4-O-benzyl-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside (460741-89-3)

Guidance literature:

With aluminium trichloride; trimethylamine-borane; In diethyl ether; dichloromethane;

DOI:10.1055/s-2002-31933

Reference yield: 92.0%

2-(azidomethyl)benzoyl chloride (289712-58-9) + ethylthio 2-O-benzoyl-4-O-benzyl-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside (460741-89-3) → ethylthio 6-O-(2-(azidomethyl)benzoyl)-2-O-benzoyl-4-O-benzyl-3-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside (1259036-11-7)

Guidance literature:

With dmap; In dichloromethane; at 20 ℃; for 0.5h;

DOI:10.1039/c0cc03153d

Reference yield: 64.0%

benzyl bromide (100-39-0) + ethylthio 2-O-benzoyl-4-O-benzyl-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside (460741-89-3) → Benzoic acid (2S,3R,4S,5R,6R)-5-benzyloxy-6-benzyloxymethyl-4-(tert-butyl-dimethyl-silanyloxy)-2-ethylsulfanyl-tetrahydro-pyran-3-yl ester (460741-91-7)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; sodium hydride; In N,N-dimethyl-formamide;

DOI:10.1055/s-2002-31933

upstream raw materials:

ethyl 2-O-benzoyl-4,6-O-benzylidene-3-O-(tert-butyldimethylsilyl)-1-thio-β-D-glucopyranoside

Downstream raw materials:

Benzoic acid (2S,3R,4S,5R,6R)-5-benzyloxy-6-benzyloxymethyl-4-(tert-butyl-dimethyl-silanyloxy)-2-ethylsulfanyl-tetrahydro-pyran-3-yl ester

Benzoic acid (2S,3R,4S,5R,6R)-5-benzyloxy-2-ethylsulfanyl-4-(9H-fluoren-9-ylmethoxycarbonyloxy)-6-hydroxymethyl-tetrahydro-pyran-3-yl ester

4-Methyl-benzoic acid (2R,3R,4S,5R,6R)-2-[(2R,3R,4S,5R,6S)-5-benzoyloxy-3-benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-6-ethylsulfanyl-tetrahydro-pyran-2-ylmethoxy]-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester

4-Methyl-benzoic acid (2R,3R,4S,5R,6R)-2-[(2R,3R,4S,5R,6S)-5-benzoyloxy-3-benzyloxy-6-ethylsulfanyl-4-(9H-fluoren-9-ylmethoxycarbonyloxy)-tetrahydro-pyran-2-ylmethoxy]-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 460741-89-3 ethylthio 2-O-benzoyl-4-O-benzyl-3-O-tert-butyldimethylsilyl-β-D-glucopyranoside

Send

Send

Metric Ton KG G Pound L ML

Send

Send