trans-Mn(CO)4{P(OPh)3}2BF₄

Base Information

Chemical Name:trans-Mn(CO)4{P(OPh)3}2BF₄
CAS No.:117686-85-8
Molecular Formula:BF₄*C₄₀H₃₀MnO₁₀P₂
Molecular Weight:874.362
Hs Code.:

Synonyms:trans-Mn(CO)4{P(OPh)3}2BF₄

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Chemical Property of trans-Mn(CO)4{P(OPh)3}2BF₄

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Technology Process of trans-Mn(CO)4{P(OPh)3}2BF₄

There total 1 articles about trans-Mn(CO)4{P(OPh)3}2BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 14104-20-2
silver tetrafluoroborate

: 15614-85-4
mer,trans-BrMn(CO)3{P(OPh)3}2

: 117686-85-8
trans-Mn(CO)4{P(OPh)3}2BF₄

Guidance literature:: With carbon monoxide; In dichloromethane; refluxing soln. of mer,trans-BrMn(CO)3(P(OPh)3)2 with stirring while bubbling CO through the soln., then addn. of AgBF4, further addn. of AgBF4 after 7 and 14 h of heating, heating continued till total of 20 h, cooling to room temp.; filtration through Celite, concn., addn. to hexane-ether (3:1), keeping at 0 ° C, pptn., redissolution in THF and addn. of ether, pptn.; react. monitored by IR, elem. anal.;

Reference yield: 95.0%

: 117686-85-8
trans-Mn(CO)4{P(OPh)3}2BF₄

: mer,trans-Mn(CO)3(P(OPh)3)2CHO

Guidance literature:: With Et₄NBH₄; In acetonitrile; soln. of Mn-complex in MeCN was treated at room temp. with a molar equiv of Et4NBH4; mixt. was chilled to 0°C, formyl complex was isolated by filtration under N2;
DOI:10.1021/om00155a037

Reference yield: 95.0%

: 117686-85-8
trans-Mn(CO)4{P(OPh)3}2BF₄

: tetraethylammonium borohydride

: mer,trans-Mn(CO)3(P(OPh)3)2CHO

Guidance literature:: In acetonitrile; addn. of Et4NBH4 to stirred soln. of Mn(CO)4(P(OPh)3)2BF4 at 0 ° C under N2, stirring continued for 2 min. more, pptn.; filtration under N2, washing with cold CH3CN, drying in vacuo;