1,7-diphenyl-N,N'-dioctyl-3:4,9:10-perylenetetracarboxydiimide

Base Information

• Chemical Name: 1,7-diphenyl-N,N'-dioctyl-3:4,9:10-perylenetetracarboxydiimide
• CAS No.: 1352718-28-5
• Molecular Formula: C₅₂H₅₀N₂O₄
• Molecular Weight: 766.98
• Mol file: 1352718-28-5.mol

Synonyms:1,7-diphenyl-N,N'-dioctyl-3:4,9:10-perylenetetracarboxydiimide

Chemical Property of 1,7-diphenyl-N,N'-dioctyl-3:4,9:10-perylenetetracarboxydiimide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,7-diphenyl-N,N'-dioctyl-3:4,9:10-perylenetetracarboxydiimide

There total 3 articles about 1,7-diphenyl-N,N'-dioctyl-3:4,9:10-perylenetetracarboxydiimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

N,N'-bis(n-octyl)-1,7-dibromo-perylene-3,4:9,10-bis(dicarboximide) (209111-67-1) + phenylboronic acid (98-80-6) → 1,7-diphenyl-N,N'-dioctyl-3:4,9:10-perylenetetracarboxydiimide (1352718-28-5)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In ethanol; water; toluene; at 80 ℃; for 3h; Inert atmosphere;

DOI:10.1002/ejoc.201402625

Reference yield:

1,6-dibromo-N,N'-di(2-ethylhexyl)-perylene-3,4,9,10-tetracarboxydiimide + 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole (24388-23-6) + N,N'-bis(n-octyl)-1,7-dibromo-perylene-3,4:9,10-bis(dicarboximide) (209111-67-1) → 1,7-diphenyl-N,N'-dioctyl-3:4,9:10-perylenetetracarboxydiimide (1352718-28-5) + 1,6-diphenyl-N,N'-dioctyl-3:4,9:10-perylenetetracarboxydiimide (1379575-16-2)

Guidance literature:

With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; tetrabutyl-ammonium chloride; potassium carbonate; In water; toluene; at 90 ℃; for 16h; regiospecific reaction; Inert atmosphere;

DOI:10.1002/ejoc.201101825

Reference yield:

bromobenzene (108-86-1,52753-63-6) + n-Octylamine (111-86-4) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) + bis(pinacol)diborane (73183-34-3) → 1,7-diphenyl-N,N'-dioctyl-3:4,9:10-perylenetetracarboxydiimide (1352718-28-5) + 1,6-diphenyl-N,N'-dioctyl-3:4,9:10-perylenetetracarboxydiimide (1379575-16-2)

Guidance literature:

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride; With sulfuric acid; bromine; at 85 ℃;

n-Octylamine; With propionic acid; Reflux;

bromobenzene; bis(pinacol)diborane; Further stages;

DOI:10.1002/ejoc.201101051

upstream raw materials:

bromobenzene

n-Octylamine

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

bis(pinacol)diborane