((trimethylsilyl)methyl)(5,10,15,20-tetramesitylporphyrinato)rhodium(III)

Base Information

Chemical Name:((trimethylsilyl)methyl)(5,10,15,20-tetramesitylporphyrinato)rhodium(III)
CAS No.:927403-45-0
Molecular Formula:C₆₀H₆₃N₄RhSi
Molecular Weight:971.178
Hs Code.:

Synonyms:((trimethylsilyl)methyl)(5,10,15,20-tetramesitylporphyrinato)rhodium(III)

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Chemical Property of ((trimethylsilyl)methyl)(5,10,15,20-tetramesitylporphyrinato)rhodium(III)

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Technology Process of ((trimethylsilyl)methyl)(5,10,15,20-tetramesitylporphyrinato)rhodium(III)

There total 2 articles about ((trimethylsilyl)methyl)(5,10,15,20-tetramesitylporphyrinato)rhodium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 121393-39-3
5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)

: 18107-18-1
diazomethyl-trimethyl-silane

: 927403-45-0
((trimethylsilyl)methyl)(5,10,15,20-tetramesitylporphyrinato)rhodium(III)

Guidance literature:: In diethyl ether; benzene; (trimethylsilyl)diazomethane in ether was added to soln. Rh complex in benzene and stirred for 30 min under N2 atm. in absence of light; chromy. on silica (hexane-CH2Cl2 10:1 to 5:1); elem. anal.;
DOI:10.1021/om060833j

Reference yield: 63.0%

: 161407-97-2
(5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride

: 2344-80-1
Chloromethyltrimethylsilane

: 927403-45-0
((trimethylsilyl)methyl)(5,10,15,20-tetramesitylporphyrinato)rhodium(III)

Guidance literature:: With sodium hydroxide; sodium tetrahydroborate; In ethanol; under N2 atm. to suspn. Rh complex in EtOH and soln. NaBH4 in 0.5 M NaOHwas added and heated at 55°C for 1 h, react. mixt. was cooled to room temp., ClCH2SiMe3 was added and stirred for 1 h at room temp.; CH2Cl2 and H2O were added, product was extd. with CH2Cl2, washed with water, dried over MgSO4, filtered and evapd. to dryness, column chromy. onsilica (hexane-CH2Cl2 10 to 51);
DOI:10.1021/om060833j