1-(2-iodoethynyl)ferrocene

Base Information

Chemical Name:1-(2-iodoethynyl)ferrocene
CAS No.:94598-10-4
Molecular Formula:C₁₂H₉FeI
Molecular Weight:335.955
Hs Code.:

Synonyms:1-(2-iodoethynyl)ferrocene

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Chemical Property of 1-(2-iodoethynyl)ferrocene

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Technology Process of 1-(2-iodoethynyl)ferrocene

There total 1 articles about 1-(2-iodoethynyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.7%

: 1271-47-2
ferroceneacetylene

: 1600-27-7
mercury(II) diacetate

: 1271-55-2
acetylferrocene

: 94598-10-4
1-(2-iodoethynyl)ferrocene

: 2‐iodoacetylferrocene

Guidance literature:: With methanol; iodine; In methanol; byproducts: CH3OCH3, CH3CO2H, CH3OHgOC(O)CH3; mercuric acetate in anhydrous methanol added dropwise (over a period of10-15 min) to a stirred soln. of ethynylferrocene at room temp. under N2, pptd., 16 h, molar ratio of FcCCH/Hg(OAc)2: 1.00/1.25, excess of I2 in either CH3OH or CH2Cl2 added; mixture poured into water and CCl4, organic phase sepd., treated twice with 10% aq. Na2S2O3, washed with water, dried over anhydrous Na2SO4, excess I2 removed, GC;
DOI:10.1021/om00123a001

Reference yield: 87.0%

: 94598-10-4
1-(2-iodoethynyl)ferrocene

: [Co3(μ-bis(diphenylphosphino)methane)(CO)7(μ3-C(CC)2)Au(triphenylphosphine))]

: 916606-14-9
Co3(μ3-C(CC)3Fc)(μ-dppm)(CO)7

Guidance literature:: With CuI; Pd(P(C₆H₅)3)4; In tetrahydrofuran; (N2); stirred at room temp. for 30 min; evapd., dissolved in CH2Cl2, chromd. (silica gel, acetone/hexane); elem.anal.;
DOI:10.1016/j.jorganchem.2008.06.007

Reference yield: 87.0%

: 94598-10-4
1-(2-iodoethynyl)ferrocene

: [Co3(μ-bis(diphenylphosphino)methane)(CO)7(μ3-CCCAu(triphenylphosphine))]

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

: 1273-18-3
1,4-bis(ferrocenyl)-1,3-butadiyne

: [Co3(μ3-CC2C2Fc)(μ-bis(diphenylphosphino)methane)(CO)7]

Guidance literature:: copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; a mixt. in THF was stirred at room temp. for 1 h (Ar); evapd., preparative TLC (acetone-hexane), crystd. from C6H6-hexane; elem. anal.;
DOI:10.1016/j.jorganchem.2003.08.006