2,4,6-tris[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]-1,3,5-triazine

Base Information

• Chemical Name: 2,4,6-tris[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]-1,3,5-triazine
• CAS No.: 639800-44-5
• Molecular Formula: C₇₂H₈₁N₉O₆
• Molecular Weight: 1168.49
• Mol file: 639800-44-5.mol

Synonyms:2,4,6-tris[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]-1,3,5-triazine

Chemical Property of 2,4,6-tris[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]-1,3,5-triazine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,4,6-tris[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]-1,3,5-triazine

There total 1 articles about 2,4,6-tris[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]-1,3,5-triazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

1,3,5-trichloro-2,4,6-triazine (108-77-0) + 3,5-bis(4-(butyloxy)phenyl)-1H-pyrazole (152462-10-7) → 2,4,6-tris[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]-1,3,5-triazine (639800-44-5)

Guidance literature:

3,5-bis(4-(butyloxy)phenyl)-1H-pyrazole; With sodium hydride; In tetrahydrofuran; at 90 ℃; for 1.5h;

1,3,5-trichloro-2,4,6-triazine; In tetrahydrofuran; at 60 - 90 ℃; for 26h;

DOI:10.1002/ejic.200300039

Reference yield: 75.0%

silver tetrafluoroborate (14104-20-2) + bis(η3-allyl-μ-chloropalladium(II)) + 2,4,6-tris[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]-1,3,5-triazine (639800-44-5) → Pd2(μ-C3H5)2[[(C6H4OC4H9)2C3HN3]2C3N3O]BF4

Guidance literature:

In acetone; byproducts: [[(C6H4OC4H9)2C3HN2H2]BF4; (N2), AgBF4 added to Pd complex in acetone in the darkness, filtered (Celite), cooled (ice bath), treated with ligand, stirred for 5 h; evapd.(vac.), crystd.(CH2Cl2/hexaane), elem. anal.;

DOI:10.1002/ejic.200300039

Reference yield: 60.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + silver nitrate + 2,4,6-tris[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]-1,3,5-triazine (639800-44-5) → [3,5-bis(4-butoxyphenyl)-1H-pyrazolato]bis(triphenylphosphine)digold nitrate + Au3[2,4,6-tris[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]-1,3,5-triazine][PPh3]3(NO3)3

Guidance literature:

In dichloromethane; acetone; (N2), AgBF4 added to Au complex in acetone, stirred for 2h in the darkness, filtered (Celite), evapd., treated with ligand in CH2Cl2, stirred for 5 h at room temp.; evapd.(vac.), crystd.(CH2Cl2/hexane), recrystd.(CH2Cl2/diethyl ether), elem. anal.;

DOI:10.1002/ejic.200300039

upstream raw materials:

1,3,5-trichloro-2,4,6-triazine

3,5-bis(4-(butyloxy)phenyl)-1H-pyrazole

Downstream raw materials:

[Ag₃(2,4,6-tris[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]-1,3,5-triazine)(OSO₂CF₃)3]