C₇₁H₉₂O₁₀Si

Base Information

• Chemical Name: C₇₁H₉₂O₁₀Si
• CAS No.: 854749-33-0
• Molecular Formula: C₇₁H₉₂O₁₀Si
• Molecular Weight: 1133.59
• Mol file: 854749-33-0.mol

Synonyms:C₇₁H₉₂O₁₀Si

Chemical Property of C₇₁H₉₂O₁₀Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₇₁H₉₂O₁₀Si

There total 7 articles about C₇₁H₉₂O₁₀Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

(4S,6S)-8-(tert-Butyl-diphenyl-silanyloxy)-6-(4-methoxy-benzyloxy)-2-trimethylsilanylmethyl-oct-1-en-4-ol (854749-31-8) + [(2S,6R)-6-((E)-3-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-3-methyl-but-1-enyl)-4-methylene-tetrahydro-pyran-2-yl]-acetaldehyde (854749-32-9) → C71H92O10Si (854749-33-0)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In diethyl ether; at -78 ℃;

DOI:10.1021/ol050512o

Reference yield:

(S)-5-((tert-butyldiphenylsilyl)oxy)-3-((4-methoxybenzyl)oxy)pentanal (854749-30-7) → C71H92O10Si (854749-33-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 100 percent / MgBr₂*Et₂O / -78 °C

2: 80 percent / trimethylsilyl triflate / diethyl ether / -78 °C

With trimethylsilyl trifluoromethanesulfonate; magnesium bromide; In diethyl ether;

DOI:10.1021/ol050512o

Reference yield:

2-[(2S,6R)-6-((E)-3-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-3-methyl-but-1-enyl)-4-methylene-tetrahydro-pyran-2-yl]-ethanol → C71H92O10Si (854749-33-0)

Guidance literature:

Multi-step reaction with 2 steps

1: tertapropylammonium perruthenate; N-methylmorpholine N-oxide

2: 80 percent / trimethylsilyl triflate / diethyl ether / -78 °C

With tetrapropylammonium perruthennate; trimethylsilyl trifluoromethanesulfonate; 4-methylmorpholine N-oxide; In diethyl ether;

DOI:10.1021/ol050512o

upstream raw materials:

(4S,6S)-8-(tert-Butyl-diphenyl-silanyloxy)-6-(4-methoxy-benzyloxy)-2-trimethylsilanylmethyl-oct-1-en-4-ol

[(2S,6R)-6-((E)-3-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-3-methyl-but-1-enyl)-4-methylene-tetrahydro-pyran-2-yl]-acetaldehyde

(S)-5-((tert-butyldiphenylsilyl)oxy)-3-((4-methoxybenzyl)oxy)pentanal

{2-[(2S,6R)-6-((E)-3-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-3-methyl-but-1-enyl)-4-methylene-tetrahydro-pyran-2-yl]-ethoxy}-tert-butyl-diphenyl-silane

Downstream raw materials:

6-[3-benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-2-[3-(6-{6-[4-hydroxy-2-(4-methoxy-benzyloxy)-butyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-4-methylene-tetrahydro-pyran-2-yl)-1,1-dimethyl-allyl]-2-methoxy-tetrahydro-pyran-3-ol

(R)-4-[(2S,6R)-6-((2S,6R)-6-{(E)-3-[(2S,6S)-6-((2R,3R)-3-Benzyloxymethoxy-2-hydroxy-butyl)-2-methoxy-3-oxo-tetrahydro-pyran-2-yl]-3-methyl-but-1-enyl}-4-methylene-tetrahydro-pyran-2-ylmethyl)-4-methylene-tetrahydro-pyran-2-yl]-3-hydroxy-butyric acid

C₄₀H₅₆O₁₀