[N,N'-bis(2-hydroxy-3-methoxybenzylidine)-1,3-diaminopropane]copper(II)

Base Information

• Chemical Name: [N,N'-bis(2-hydroxy-3-methoxybenzylidine)-1,3-diaminopropane]copper(II)
• CAS No.: 57638-78-5
• Molecular Formula: C₁₉H₂₀N₂O₄*Cu
• Molecular Weight: 403.925
• Mol file: 57638-78-5.mol

Synonyms:[N,N'-bis(2-hydroxy-3-methoxybenzylidine)-1,3-diaminopropane]copper(II)

Chemical Property of [N,N'-bis(2-hydroxy-3-methoxybenzylidine)-1,3-diaminopropane]copper(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [N,N'-bis(2-hydroxy-3-methoxybenzylidine)-1,3-diaminopropane]copper(II)

There total 3 articles about [N,N'-bis(2-hydroxy-3-methoxybenzylidine)-1,3-diaminopropane]copper(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

copper(II) nitrate trihydrate + 3-methoxy-2-hydroxybenzaldehyde (148-53-8) + Trimethylenediamine (109-76-2,54018-94-9) → [Cu(valpn)] (57638-78-5)

Guidance literature:

With triethylamine; In ethanol; Reflux;

DOI:10.1016/j.ica.2017.06.058

Reference yield:

Cu4I4(pyridine)4 + {NiOC6H3(3-OCH3)CHN(CH2)3NCHC6H3(3-OCH3)} (22523-89-3) → (Ni(OH))2(Ni(H2O)2(CH3O(O)C6H3CHN(CH2)3NCHC6H3(O)OCH3))2(CH3COCH3)4(2+)*Cu2I4(2-)={C50H74N4Ni4O18}(2+)*{Cu2I4}(2-) + [Cu(valpn)] (57638-78-5)

Guidance literature:

In acetone; Ni(mepren) and (CuIpy)4 are refluxed in acetone for 24 h.; Recrystn. from acetone yields three crystalline products;

DOI:10.1039/c39900000959

Reference yield:

copper(II) acetate monohydrate (6046-93-1) + 3-methoxy-2-hydroxybenzaldehyde (148-53-8) + Trimethylenediamine (109-76-2,54018-94-9) → [Cu(valpn)] (57638-78-5)

Guidance literature:

3-methoxy-2-hydroxybenzaldehyde; Trimethylenediamine; In methanol; for 0.166667h;

copper(II) acetate monohydrate; for 2h; Reflux;

DOI:10.1039/c6nj01887d

upstream raw materials:

{NiOC₆H₃(3-OCH₃)CHN(CH₂)3NCHC₆H₃(3-OCH₃)}

copper(II) acetate monohydrate

3-methoxy-2-hydroxybenzaldehyde

Trimethylenediamine