acetylacetonato(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)nickel(II) perchlorate

Base Information

• Chemical Name: acetylacetonato(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)nickel(II) perchlorate
• CAS No.: 872993-24-3
• Molecular Formula: C₄₅H₃₇N₄NiO₃*ClO₄
• Molecular Weight: 839.954
• Mol file: 872993-24-3.mol

Synonyms:acetylacetonato(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)nickel(II) perchlorate

Chemical Property of acetylacetonato(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)nickel(II) perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of acetylacetonato(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)nickel(II) perchlorate

There total 1 articles about acetylacetonato(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)nickel(II) perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

nickel(II) perchlorate hexahydrate + N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine (167897-42-9) + 2-hydroxy-1,3-diphenyl-propane-1,3-dione (4720-56-3) → acetylacetonato(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)nickel(II) perchlorate (872993-24-3)

Guidance literature:

With tetramethyl ammoniumhydroxide; In acetonitrile; (N2); mixing of pyridine deriv., nickel compd., tetramethylammonium hydroxyde and diketone in CH3CN; evapn., dissolving in CH2Cl2, filtration through Celite, addn. of pentane;

DOI:10.1021/ja056346x

Reference yield: 75.0%

acetylacetonato(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)nickel(II) perchlorate (872993-24-3) + oxygen (80937-33-3) → (N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine)Ni(PhCO2)2H2O

Guidance literature:

With tetramethyl ammoniumhydroxide; In acetonitrile; byproducts: CO; addn. of tetramethylammonium hydroxyde to nickel compd., addn. of excessO2; elem. anal.;

DOI:10.1021/ja056346x

Reference yield:

acetylacetonato(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)nickel(II) perchlorate (872993-24-3) + oxygen-18 (32767-18-3) → (N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine)Ni(PhCO(18)O)2H2O

Guidance literature:

With tetramethyl ammoniumhydroxide; In acetonitrile; byproducts: CO; addn. of tetramethylammonium hydroxyde to nickel compd., addn. of excessO2;

DOI:10.1021/ja056346x

upstream raw materials:

N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine

2-hydroxy-1,3-diphenyl-propane-1,3-dione

Downstream raw materials:

benzoato(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)nickel(II) perchlorate