cumylperoxytrimethylsilane

Base Information

• Chemical Name: cumylperoxytrimethylsilane
• CAS No.: 18057-16-4
• Molecular Formula: C12H20 O2 Si
• Molecular Weight: 224.375
• Mol file: 18057-16-4.mol

Synonyms:Peroxide, a,a-dimethylbenzyl trimethylsilyl (6CI); Silane, [(a,a-dimethylbenzyl)dioxy]trimethyl- (8CI); (a,a-Dimethylbenzylperoxy)trimethylsilane;2-Phenyl-2-[(trimethylsilyl)peroxy]propane; Cumyl trimethylsilyl peroxide; a,a-Dimethylbenzyl trimethylsilyl peroxide

Chemical Property of cumylperoxytrimethylsilane

Chemical Property:

• PSA: 18.46000
• LogP: 3.70480

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of cumylperoxytrimethylsilane

There total 3 articles about cumylperoxytrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

chloro-trimethyl-silane (75-77-4) + Cumene hydroperoxide (80-15-9) → trimethylsilyl(cumyl) peroxide (18057-16-4)

Guidance literature:

With triethylamine; In hexane; at 0 - 20 ℃; for 1h;

DOI:10.1021/jacs.1c12649

Reference yield:

chloro-trimethyl-silane (75-77-4) + DABCO·2CHP → trimethylsilyl(cumyl) peroxide (18057-16-4)

Guidance literature:

DABCO·2CHP; With 1,4-diaza-bicyclo[2.2.2]octane; In hexane; at 0 ℃; for 0.0833333h;

chloro-trimethyl-silane; In hexane; at 0 - 20 ℃;

DOI:10.1002/rcm.8282

Reference yield:

Cumene hydroperoxide (80-15-9) → trimethylsilyl(cumyl) peroxide (18057-16-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: hexane

2.1: 1,4-diaza-bicyclo[2.2.2]octane / hexane / 0.08 h / 0 °C

2.2: 0 - 20 °C

With 1,4-diaza-bicyclo[2.2.2]octane; In hexane;

DOI:10.1002/rcm.8282

upstream raw materials:

chloro-trimethyl-silane

Cumene hydroperoxide

Downstream raw materials:

1-methyl-1-phenylethyl alcohol

Methoxy-dimethyl-(1-methyl-1-phenyl-ethoxy)-silane

acetophenone

(1-methyl-1-phenyl-ethyl)-trityl peroxide

Refernces

• 1、 Krawczyk, Tomasz,Zalewski, Mariusz,Szo?tysik, Rafa?,Korytkowska-Wa?ach, Anna. "Determination of silyl peroxides by ultra-performance liquid chromatography/electrospray ionisation mass spectrometry". . p. 2040 - 2046. Retrieved 2018/11/10.