N-benzyl-N',N''-bis(3,5-di-tert-butylsalicylidene)pyrrolidine-3R,4R-diamine oxide

Base Information

• Chemical Name: N-benzyl-N',N''-bis(3,5-di-tert-butylsalicylidene)pyrrolidine-3R,4R-diamine oxide
• CAS No.: 1334106-63-6
• Molecular Formula: C₄₁H₅₇N₃O₃
• Molecular Weight: 639.922
• Mol file: 1334106-63-6.mol

Synonyms:N-benzyl-N',N''-bis(3,5-di-tert-butylsalicylidene)pyrrolidine-3R,4R-diamine oxide

Chemical Property of N-benzyl-N',N''-bis(3,5-di-tert-butylsalicylidene)pyrrolidine-3R,4R-diamine oxide

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of N-benzyl-N',N''-bis(3,5-di-tert-butylsalicylidene)pyrrolidine-3R,4R-diamine oxide

There total 1 articles about N-benzyl-N',N''-bis(3,5-di-tert-butylsalicylidene)pyrrolidine-3R,4R-diamine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

(3R,4R)-N3,N4-bis[3,5-di-t-butylsalicylidene]-1-benzyl-3,4-diaminopyrrolidine (1021949-25-6) → N-benzyl-N',N''-bis(3,5-di-tert-butylsalicylidene)pyrrolidine-3R,4R-diamine oxide (1334106-63-6)

Guidance literature:

With potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 ℃; for 10h; Inert atmosphere;

DOI:10.1002/ejoc.201100319

Reference yield:

N-benzyl-N',N''-bis(3,5-di-tert-butylsalicylidene)pyrrolidine-3R,4R-diamine oxide (1334106-63-6) + diethylaluminium chloride (96-10-6) → C41H55AlClN3O3

Guidance literature:

In dichloromethane; at 20 ℃; for 10h; Temperature; Reagent/catalyst; Catalytic behavior; Inert atmosphere;

DOI:10.1016/j.catcom.2012.06.025

Reference yield:

titanium(IV) isopropylate (546-68-9) + N-benzyl-N',N''-bis(3,5-di-tert-butylsalicylidene)pyrrolidine-3R,4R-diamine oxide (1334106-63-6) → C47H69N3O5Ti

Guidance literature:

In dichloromethane; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1002/ejoc.201100319

upstream raw materials:

(3R,4R)-N₃,N₄-bis[3,5-di-t-butylsalicylidene]-1-benzyl-3,4-diaminopyrrolidine