4-fluoro-2,4,6-trimethyldiphenyliodonium trifluoromethanesulfonate

Base Information

• Chemical Name: 4-fluoro-2,4,6-trimethyldiphenyliodonium trifluoromethanesulfonate
• CAS No.: 1146127-04-9
• Molecular Formula: CF₃O₃S*C₁₅H₁₅FI
• Molecular Weight: 490.257
• Mol file: 1146127-04-9.mol

Synonyms:4-fluoro-2,4,6-trimethyldiphenyliodonium trifluoromethanesulfonate

Chemical Property of 4-fluoro-2,4,6-trimethyldiphenyliodonium trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-fluoro-2,4,6-trimethyldiphenyliodonium trifluoromethanesulfonate

There total 1 articles about 4-fluoro-2,4,6-trimethyldiphenyliodonium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

trifluorormethanesulfonic acid (1493-13-6) + 4-fluoro-1-iodobenzene (352-34-1) + 1,3,5-trimethyl-benzene (108-67-8) → 4-fluoro-2,4,6-trimethyldiphenyliodonium trifluoromethanesulfonate (1146127-04-9)

Guidance literature:

In acetonitrile; Electrochemical reaction; Green chemistry;

DOI:10.1039/d1ob00457c

Reference yield: 90.0%

4-fluoro-2,4,6-trimethyldiphenyliodonium trifluoromethanesulfonate (1146127-04-9) + phosphonic acid diethyl ester (762-04-9) → thiophosphoric acid O,O'-diethyl ester S-(4-fluorophenyl) ester (333-42-6)

Guidance literature:

With copper acetylacetonate; sulfur; triethylamine; In acetonitrile; at 20 ℃; for 20h; Green chemistry;

DOI:10.1021/acs.joc.6b00925

Reference yield: 89.0%

4-fluoro-2,4,6-trimethyldiphenyliodonium trifluoromethanesulfonate (1146127-04-9) + N-(2-(cyclopropylidene(phenyl)methyl)phenyl)-N-methylmethacrylamide → 7-(4-fluorobenzyl)-5,7-dimethyl-5,7,8,9-tetrahydro-6H-benzo[b]naphtho[1,2-d]azepin-6-one

Guidance literature:

With sodium hydrogencarbonate; copper(I) bromide; In chlorobenzene; at 120 ℃; for 2h; Schlenk technique; Inert atmosphere;

DOI:10.1039/c7ob02502e

upstream raw materials:

trifluorormethanesulfonic acid

4-fluoro-1-iodobenzene

1,3,5-trimethyl-benzene

Downstream raw materials:

4'-dibenzylamino-4''-fluoro-[1,1';3',1'']terphenyl-4-carboxylic acid ethyl ester

(R)-3-(2-(benzyloxy)-2-(4-fluorophenyl)acetyl)oxazolidin-2-one

(R)-3-(2-(4-fluorophenyl)propanoyl)oxazolidin-2-one

4-fluorobenzonitrile