(Bromomethoxy)(dimethoxy)phenylsilane

Base Information

• Chemical Name: (Bromomethoxy)(dimethoxy)phenylsilane
• CAS No.: 17043-05-9
• Molecular Formula: C9H13BrO3Si
• Molecular Weight: 277.19
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID30700864
• Wikidata: Q82632347
• Mol file: 17043-05-9.mol

Synonyms:SCHEMBL445218;DTXSID30700864;(Bromomethoxy)(dimethoxy)phenylsilane

Chemical Property of (Bromomethoxy)(dimethoxy)phenylsilane

Chemical Property:

• Vapor Pressure: 0.099mmHg at 25°C
• Refractive Index: 1.5390
• Boiling Point: 230.532 °C at 760 mmHg
• Flash Point: 93.223 °C
• PSA: 27.69000
• Density: 1.339 g/cm³
• LogP: 1.53420
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 275.98173
• Heavy Atom Count: 14
• Complexity: 158

Purity/Quality:

98%,99%, ^*data from raw suppliers

BROMOPHENYLTRIMETHOXYSILANE (MIXED ISOMERS) 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 9-16-36/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CO[Si](C1=CC=CC=C1)(OC)OCBr

Technology Process of (Bromomethoxy)(dimethoxy)phenylsilane

There total 3 articles about (Bromomethoxy)(dimethoxy)phenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chlorotrimethoxysilane (4668-00-2) + (4-bromophenyl)magnesium bromide (18620-02-5) → 4-bromo-1-(trimethoxysilyl)benzene (17043-05-9)

Guidance literature:

In tetrahydrofuran; a) RT, overnight, b) reflux, 1 h;

DOI:10.1039/a801077c

Reference yield:

methanol (67-56-1) + (4-bromophenyl)trichlorosilane (18164-08-4) → 4-bromo-1-(trimethoxysilyl)benzene (17043-05-9)

Guidance literature:

Reference yield:

→ 4-bromo-1-(trimethoxysilyl)benzene (17043-05-9)

Guidance literature:

upstream raw materials:

methanol

(4-bromophenyl)trichlorosilane

chlorotrimethoxysilane

(4-bromophenyl)magnesium bromide

Downstream raw materials:

4-bromo-N-phenyl-benzamide

5-(4-bromophenyl)silatrane

1-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)silatrane

5-(4-ethynylphenyl)silatrane

Refernces