TRIMETHYLSILYLPERRHENATE

Base Information

• Chemical Name: TRIMETHYLSILYLPERRHENATE
• CAS No.: 16687-12-0
• Molecular Formula: C3H9 O4 Re Si
• Molecular Weight: 323.395
• Hs Code.: 2931900090
• Mol file: 16687-12-0.mol

Synonyms:Perrhenicacid (HReO4), trimethylsilyl ester; Silanol, trimethyl-, ester with perrhenicacid (HReO4) (8CI); Silanol, trimethyl-, perrhenate (6CI); Silanol, trimethyl-,rhenium complex; Trimethylsilyl perrhenate; Trimethylsilyl perrhenate(Me3SiReO4); Trioxo(trimethylsilanolato)rhenium; Trioxo(trimethylsiloxy)rhenium

Chemical Property of TRIMETHYLSILYLPERRHENATE

Chemical Property:

• Melting Point: 79-81°C
• Boiling Point: 65-75°C 1mm
• Flash Point: >65°C
• PSA: 60.44000
• LogP: 0.94580
• Storage Temp.: below 5° C

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRIMETHYLSILYLPERRHENATE

There total 3 articles about TRIMETHYLSILYLPERRHENATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro-trimethyl-silane (75-77-4) + silver(I) perrhenate → trimethylsilylperrhenate (16687-12-0)

Guidance literature:

In acetonitrile;

DOI:10.1007/s12039-021-02000-6

Reference yield:

N-Trimethylsilyl (116467-64-2) + rhenium(VII) oxide → cis-{ReO(OSiMe3)(PPh2CH2PPh2N)2}(ReO4)2 + trimethylsilylperrhenate (16687-12-0)

Guidance literature:

In not given;

Reference yield:

→ trimethylsilylperrhenate (16687-12-0)

Guidance literature:

Re2O7, Hexamethyldisiloxan;

DOI:10.1002/zaac.19723930108

upstream raw materials:

N-Trimethylsilyl

chloro-trimethyl-silane

Downstream raw materials:

2,6-dimethylaniline hydrochloride

(2,6-iPr₂C₆H₃N)3ReORe(O)(N-2,6-C₆H₃iPr₂)2

dioxodi(2,6-dimethylphenyl)rhenium(VI)

Re(N-2,6-C₆H₃Me₂)3(OSiMe₃)

Refernces

• 1、 Cavell, Ronald G.,Reed, Robert W.,Katti, Kattesh V.,Balakrishna, Maravanji S.,Collins, Paul W.,et al.. "HETEROBIFUNCTIONAL PHOSPHORUS-NITROGEN COMPOUNDS: IMINOPHOSPHORANOPHOSPHINES AND THEIR COMPLEXES.". . p. 9 - 12. Retrieved 2007/10/02.