methyl (2R,3R)-3-methyl-3-{(2RS)-2-methyl-12-phenyl-2-[(triethylsilyl)peroxy]dodecyl}oxirane-2-carboxylate

Base Information

Chemical Name:methyl (2R,3R)-3-methyl-3-{(2RS)-2-methyl-12-phenyl-2-[(triethylsilyl)peroxy]dodecyl}oxirane-2-carboxylate
CAS No.:1341216-73-6
Molecular Formula:C₃₀H₅₂O₅Si
Molecular Weight:520.825
Hs Code.:

Synonyms:methyl (2R,3R)-3-methyl-3-{(2RS)-2-methyl-12-phenyl-2-[(triethylsilyl)peroxy]dodecyl}oxirane-2-carboxylate

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Chemical Property of methyl (2R,3R)-3-methyl-3-{(2RS)-2-methyl-12-phenyl-2-[(triethylsilyl)peroxy]dodecyl}oxirane-2-carboxylate

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Technology Process of methyl (2R,3R)-3-methyl-3-{(2RS)-2-methyl-12-phenyl-2-[(triethylsilyl)peroxy]dodecyl}oxirane-2-carboxylate

There total 10 articles about methyl (2R,3R)-3-methyl-3-{(2RS)-2-methyl-12-phenyl-2-[(triethylsilyl)peroxy]dodecyl}oxirane-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 617-86-7
triethylsilane

: 1341216-70-3
methyl (2R,3R)-3-methyl-3-(2-methylene-12-phenyldodecyl)oxirane-2-carboxylate

: 1341216-73-6
methyl (2R,3R)-3-methyl-3-{(2RS)-2-methyl-12-phenyl-2-[(triethylsilyl)peroxy]dodecyl}oxirane-2-carboxylate

Guidance literature:: With Co(II) bis(2,2,6,6-tetramethylheptane-3,5-dienoate); oxygen; In 1,2-dichloro-ethane; at 20 ℃; for 2h; under 760.051 Torr; regioselective reaction;
DOI:10.1055/s-0030-1260959

Reference yield:

: 1341216-63-4
(R)-4-methyl-6-(10-phenyldecyl)-5,6-dihydro-2H-pyran-2-one

: 1341216-73-6
methyl (2R,3R)-3-methyl-3-{(2RS)-2-methyl-12-phenyl-2-[(triethylsilyl)peroxy]dodecyl}oxirane-2-carboxylate

Guidance literature:: Multi-step reaction with 5 steps

1.1: dihydrogen peroxide; sodium hydroxide / methanol; water / 0 - 20 °C / Inert atmosphere

2.1: sodium hydroxide / methanol; water / 2 h / 20 °C / Inert atmosphere

2.2: 20 °C / Inert atmosphere

2.3: pH 3 - 4 / Inert atmosphere

3.1: diethyl ether; ethyl acetate / 0.17 h / 20 °C / Inert atmosphere

4.1: titanium(IV) dichlorodiisopropylate / tetrahydrofuran / 0 - 15 °C / Inert atmosphere

5.1: Co(II) bis(2,2,6,6-tetramethylheptane-3,5-dienoate); oxygen / 1,2-dichloro-ethane / 2 h / 20 °C / 760.05 Torr

With titanium(IV) dichlorodiisopropylate; Co(II) bis(2,2,6,6-tetramethylheptane-3,5-dienoate); dihydrogen peroxide; oxygen; sodium hydroxide; In tetrahydrofuran; methanol; diethyl ether; water; ethyl acetate; 1,2-dichloro-ethane;
DOI:10.1055/s-0030-1260959

Reference yield:

: C₂₂H₃₂O₄

: 1341216-73-6
methyl (2R,3R)-3-methyl-3-{(2RS)-2-methyl-12-phenyl-2-[(triethylsilyl)peroxy]dodecyl}oxirane-2-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: diethyl ether; ethyl acetate / 0.17 h / 20 °C / Inert atmosphere

2: titanium(IV) dichlorodiisopropylate / tetrahydrofuran / 0 - 15 °C / Inert atmosphere

3: Co(II) bis(2,2,6,6-tetramethylheptane-3,5-dienoate); oxygen / 1,2-dichloro-ethane / 2 h / 20 °C / 760.05 Torr

With titanium(IV) dichlorodiisopropylate; Co(II) bis(2,2,6,6-tetramethylheptane-3,5-dienoate); oxygen; In tetrahydrofuran; diethyl ether; ethyl acetate; 1,2-dichloro-ethane;
DOI:10.1055/s-0030-1260959