bis(1-pentenyl)(tetramethylcyclopentadienyl)iridium(III)(triphenylphosphine)

Base Information

Chemical Name:bis(1-pentenyl)(tetramethylcyclopentadienyl)iridium(III)(triphenylphosphine)
CAS No.:959403-49-7
Molecular Formula:C₃₇H₄₆IrP
Molecular Weight:713.966
Hs Code.:

Synonyms:bis(1-pentenyl)(tetramethylcyclopentadienyl)iridium(III)(triphenylphosphine)

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Chemical Property of bis(1-pentenyl)(tetramethylcyclopentadienyl)iridium(III)(triphenylphosphine)

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Technology Process of bis(1-pentenyl)(tetramethylcyclopentadienyl)iridium(III)(triphenylphosphine)

There total 2 articles about bis(1-pentenyl)(tetramethylcyclopentadienyl)iridium(III)(triphenylphosphine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 627097-91-0,959403-67-9
[(tetramethylcyclopentadienyl)IrCl₂(triphenylphosphine)]

: 34164-50-6
4-penten-1-ylmagnesium bromide

: 959403-49-7
bis(1-pentenyl)(tetramethylcyclopentadienyl)iridium(III)(triphenylphosphine)

Guidance literature:: In diethyl ether; (N2); using Schlenk techniques; cooling of (C5HMe4)Ir(PPh3)Cl2 in Et2O to -78°C; addn. of BrMg(CH2)3CHCH2; stirring at 0°C; treatment with satd. aq. NH4Cl at -78°C; washing of aq. layer with Et2O; sepn. of org. layer; removal of solvent under reduced pressure, recrystn. from Et2O/hexane at -10°C for 48 h; decanting; drying under vac. for several hs; elem. anal.;
DOI:10.1016/j.jorganchem.2007.07.053

Reference yield: 50.0%

: 835614-43-2
[IrCl₂(η⁵-C₅Me₄H)]₂

: 864370-43-4
cis-Pt(1-pentenyl)2(triphenylphosphine)2

: 10199-34-5,14056-88-3,15604-36-1
bis(triphenylphosphine)platinum(II) dichloride

: 627097-91-0,959403-67-9
[(tetramethylcyclopentadienyl)IrCl₂(triphenylphosphine)]

: 959403-49-7
bis(1-pentenyl)(tetramethylcyclopentadienyl)iridium(III)(triphenylphosphine)

: 175223-83-3
(CH₂CHCH₂CH₂CH₂)2Pt

Guidance literature:: In toluene; under N2, 2 equiv. of Pt-compd.a nd Ir-compd. were heated in toluene at 85-90 °C for 3 h; solvent was removed, Et2O was added, Pt(PPh3)2Cl2 and Cp(*)Ir(PPh3)2Cl2 were sepd., p-TLC (CH2Cl2), Ir-compd. was extd., treatment with n-hexane, cooling, elem. anal.;
DOI:10.1016/j.poly.2007.08.036