[(E)-2-(Methylsulfanyl)ethenyl]benzene

Base Information

• Chemical Name: [(E)-2-(Methylsulfanyl)ethenyl]benzene
• CAS No.: 15436-06-3
• Molecular Formula: C9H10 S
• Molecular Weight: 150.244
• Mol file: 15436-06-3.mol

Synonyms:Benzene,[2-(methylthio)ethenyl]-, (E)-; Sulfide, methyl styryl, (E)- (8CI);(E)-1-(Methylthio)-2-phenylethene; (E)-1-(Methylthio)-2-phenylethylene; (E)-b-(Methylthio)styrene; Methyltrans-styryl sulfide

Chemical Property of [(E)-2-(Methylsulfanyl)ethenyl]benzene

Chemical Property:

• Melting Point: 78-79 °C
• Boiling Point: 140-142 °C(Press: 35 Torr)
• PSA: 25.30000
• Density: 1.040±0.06 g/cm3(Predicted)
• LogP: 3.02030

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [(E)-2-(Methylsulfanyl)ethenyl]benzene

There total 58 articles about [(E)-2-(Methylsulfanyl)ethenyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

[(E)-2-bromoethenyl]benzene (588-72-7,1340-14-3) + sodium thiomethoxide (5188-07-8) → (E)-β-(methylthio)styrene (15436-06-3)

Guidance literature:

In N,N,N,N,N,N-hexamethylphosphoric triamide; for 1h; Ambient temperature;

DOI:10.1021/jo00173a003

Reference yield: 95.0%

[(E)-2-bromoethenyl]benzene (588-72-7,1340-14-3) + methyl iodide (74-88-4) + potassium thioacetate (10387-40-3) → (Z)-methyl(styryl)sulfane (35822-50-5) + (E)-β-(methylthio)styrene (15436-06-3)

Guidance literature:

With potassium tert-butylate; In N,N-dimethyl-formamide; at 20 - 50 ℃; for 1h;

DOI:10.1002/ejoc.201201163

Reference yield: 86.0%

methyl[(E)-1-(methylsulfinyl)-2-phenylvinyl]sulfane (35453-05-5) → methylthiol (74-93-1) + (E)-β-(methylthio)styrene (15436-06-3)

Guidance literature:

With phenol; In acetonitrile; at 27 ℃; controlled potential electrolyses at -2.3 V on Pt cathode against Ag/0.1 M AgNO₃ reference electrode in presence of 0.1 M Bu₄NBF₄;

DOI:10.1246/cl.1984.159

upstream raw materials:

[(E)-2-bromoethenyl]benzene

sodium thiomethoxide

(E)-phenyl(styryl)selane

methyl[(E)-1-(methylsulfinyl)-2-phenylvinyl]sulfane

Downstream raw materials:

2-acetyl-1,2,3,4-tetrahydro-6,7-dimethoxy-1-<1-(methylthio)-2-phenylvinyl>isoquinoline

(E)-β-(isopropylthio)styrene

(E)-2-benzyl-1,2,3,4-tetrahydro-6,7-dimethoxy-1-<1-(methylthio)-2-phenylvinyl>isoquinoline

dimethyl-phenyl-((E)-styryl)-silane