Chloro(4,4-difluorobut-3-en-1-yl)diethylsilane

Base Information

Chemical Name:Chloro(4,4-difluorobut-3-en-1-yl)diethylsilane
CAS No.:15038-82-1
Molecular Formula:C8H15 Cl F2 Si
Molecular Weight:212.7400064
Hs Code.:2931900090
DSSTox Substance ID:DTXSID90698076
Mol file:15038-82-1.mol

Synonyms:15038-82-1;Chloro(4,4-difluorobut-3-en-1-yl)diethylsilane;DTXSID90698076

Suppliers and Price of Chloro(4,4-difluorobut-3-en-1-yl)diethylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Chloro(4,4-difluorobut-3-en-1-yl)diethylsilane

Chemical Property:

PSA：0.00000
LogP:4.38100
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:5
Exact Mass:212.0599610
Heavy Atom Count:12
Complexity:151

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC[Si](CC)(CCC=C(F)F)Cl

Technology Process of Chloro(4,4-difluorobut-3-en-1-yl)diethylsilane

There total 2 articles about Chloro(4,4-difluorobut-3-en-1-yl)diethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

: 994-30-9
triethylsilyl chloride

: 62269-27-6
1-Chloro-2,2-difluoroethenyllithium

: 15038-82-1
(β-chloro difluoro vinyl) triethyl silane

Guidance literature:: In diethyl ether; reaction at -78°C, 3 hours;;
DOI:10.1021/jo01265a118

Reference yield:

: 994-30-9
triethylsilyl chloride

: 75-88-7
1,1,1-trifluoro-2-chloroethane

: 15038-82-1
(β-chloro difluoro vinyl) triethyl silane

Guidance literature:: With n-butyllithium; Multistep reaction; 1.) THF, hexane, -78 deg C, 10 min, 2.) THF, hexane, -78 deg C, 1 h; -78 to -30 deg C, 30 min;

Reference yield: 38.0%

: 15038-82-1
(β-chloro difluoro vinyl) triethyl silane

: 100-52-7
benzaldehyde

: 96502-97-5
(2-Chloro-3,3-difluoro-1-phenyl-allyloxy)-triethyl-silane

Guidance literature:: tris(diethylamino)sulfonium difluorotrimethylsiliconate; In tetrahydrofuran; for 12h; Ambient temperature;
DOI:10.1021/ja00299a059