(R)-(-)-1-[1'-(benzenesulfonyl)methyl]-2,2-dimethyl-6-methylenecyclohexane

Base Information

Chemical Name:(R)-(-)-1-[1'-(benzenesulfonyl)methyl]-2,2-dimethyl-6-methylenecyclohexane
CAS No.:502763-42-0
Molecular Formula:C₁₆H₂₂O₂S
Molecular Weight:278.415
Hs Code.:

Synonyms:(R)-(-)-1-[1'-(benzenesulfonyl)methyl]-2,2-dimethyl-6-methylenecyclohexane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R)-(-)-1-[1'-(benzenesulfonyl)methyl]-2,2-dimethyl-6-methylenecyclohexane

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Technology Process of (R)-(-)-1-[1'-(benzenesulfonyl)methyl]-2,2-dimethyl-6-methylenecyclohexane

There total 8 articles about (R)-(-)-1-[1'-(benzenesulfonyl)methyl]-2,2-dimethyl-6-methylenecyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 502763-41-9
(R)-(+)-2,2-dimethyl-6-methylene-1-[1'-(phenylthio)methyl]cyclohexane

: 502763-42-0
(R)-(-)-1-[1'-(benzenesulfonyl)methyl]-2,2-dimethyl-6-methylenecyclohexane

Guidance literature:: With Oxone; In methanol; water; at 20 ℃; for 3h;
DOI:10.1016/S0040-4020(02)01455-2

Reference yield:

: 166022-33-9
((R)-(-)-2,2-dimethyl-6-methylene-1-cyclohexyl)methanol

: 502763-42-0
(R)-(-)-1-[1'-(benzenesulfonyl)methyl]-2,2-dimethyl-6-methylenecyclohexane

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / tributylphosphine; pyridine / 15 h / 20 °C

2: 86 percent / Oxone (R) / methanol; H₂O / 3 h / 20 °C

With pyridine; Oxone; tributylphosphine; In methanol; water;
DOI:10.1016/S0040-4020(02)01455-2

Reference yield:

: 1178893-44-1
C₁₄H₂₂O₄

: 502763-42-0
(R)-(-)-1-[1'-(benzenesulfonyl)methyl]-2,2-dimethyl-6-methylenecyclohexane

Guidance literature:: Multi-step reaction with 4 steps

1: triphenylphosphine; triethylamine; bis-triphenylphosphine-palladium(II) chloride; formic acid / tetrahydrofuran / 6 h / Inert atmosphere; Reflux

2: sodium hydroxide / methanol / Reflux

3: potassium carbonate / dimethyl sulfoxide / 12 h / 20 °C

4: dihydrogen peroxide; ammonium molibdate / methanol / 8 h / 0 - 20 °C

With bis-triphenylphosphine-palladium(II) chloride; ammonium molibdate; formic acid; dihydrogen peroxide; potassium carbonate; triethylamine; triphenylphosphine; sodium hydroxide; In tetrahydrofuran; methanol; dimethyl sulfoxide;
DOI:10.3390/md17040245