2,2-DIMETHYL-4(R)-4-BROMOMETHYL-1,3-DIOXALANE

Base Information

Chemical Name:2,2-DIMETHYL-4(R)-4-BROMOMETHYL-1,3-DIOXALANE
CAS No.:14437-87-7
Molecular Formula:C6H11 Br O2
Molecular Weight:195.056
Hs Code.:2932999099
Mol file:14437-87-7.mol

Synonyms:1,3-Dioxolane,4-(bromomethyl)-2,2-dimethyl-, (R)- (8CI);(R)-4-(Bromomethyl)-2,2-dimethyl-1,3-dioxolane

Suppliers and Price of 2,2-DIMETHYL-4(R)-4-BROMOMETHYL-1,3-DIOXALANE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
2,2-DIMETHYL-4(R)-4-BROMOMETHYL-1,3-DIOXALANE 95.00%
5MG
$ 497.33

AK Scientific
2,2-Dimethyl-4(R)-4-bromomethyl-1,3-dioxalane
5g
$ 1680.00

Total 4 raw suppliers

Chemical Property of 2,2-DIMETHYL-4(R)-4-BROMOMETHYL-1,3-DIOXALANE

Chemical Property:

Vapor Pressure:0.688mmHg at 25°C
Refractive Index:1.453
Boiling Point:192.2°Cat760mmHg
Flash Point:74.8°C
PSA：18.46000
Density:1.359g/cm³
LogP:1.53280

Purity/Quality:

99% ^*data from raw suppliers

2,2-DIMETHYL-4(R)-4-BROMOMETHYL-1,3-DIOXALANE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xn
Hazard Codes:Xn
Statements: 22-36
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2,2-DIMETHYL-4(R)-4-BROMOMETHYL-1,3-DIOXALANE

There total 5 articles about 2,2-DIMETHYL-4(R)-4-BROMOMETHYL-1,3-DIOXALANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 83461-40-9,84806-02-0
methanesulfonic acid (R)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester

: 14437-87-7
(R)-(2,2-dimethyl-1,3-dioxolan-4-yl)methyl bromide

Guidance literature:: With 18-crown-6 ether; potassium bromide; In acetonitrile; for 48h; Heating;
DOI:10.1021/jo00139a049

Reference yield: 34.5%

: 22323-82-6,36543-79-0
(S)-(+)-(2,2-dimethyl-[1,3]dioxolan-4-yl)methanol

: 14437-87-7
(R)-(2,2-dimethyl-1,3-dioxolan-4-yl)methyl bromide

Guidance literature:: With carbon tetrabromide; triphenylphosphine; In dichloromethane; at 20 ℃;
DOI:10.1021/ja012137a

Reference yield:

: 4704-77-2
1-bromo-2,3-propanediol

: 77-76-9
2,2-dimethoxy-propane

: 14437-87-7
(R)-(2,2-dimethyl-1,3-dioxolan-4-yl)methyl bromide

: 113428-57-2
(S)-(4-bromomethyl)-2,2-dimethyl-1,3-dioxolane

Guidance literature:: With toluene-4-sulfonic acid; In dichloromethane; for 0.5h; Title compound not separated from byproducts;
DOI:10.1002/adsc.200606181