methyl 3-({[(tert-butoxycarbonyl)amino][(tert-butoxycarbonyl)imino]methyl}amino)-5-formylbenzoate

Base Information

Chemical Name:methyl 3-({[(tert-butoxycarbonyl)amino][(tert-butoxycarbonyl)imino]methyl}amino)-5-formylbenzoate
CAS No.:199536-09-9
Molecular Formula:C₂₀H₂₇N₃O₇
Molecular Weight:421.45
Hs Code.:

Synonyms:methyl 3-({[(tert-butoxycarbonyl)amino][(tert-butoxycarbonyl)imino]methyl}amino)-5-formylbenzoate

Suppliers and Price of methyl 3-({[(tert-butoxycarbonyl)amino][(tert-butoxycarbonyl)imino]methyl}amino)-5-formylbenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 3-({[(tert-butoxycarbonyl)amino][(tert-butoxycarbonyl)imino]methyl}amino)-5-formylbenzoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 3-({[(tert-butoxycarbonyl)amino][(tert-butoxycarbonyl)imino]methyl}amino)-5-formylbenzoate

There total 6 articles about methyl 3-({[(tert-butoxycarbonyl)amino][(tert-butoxycarbonyl)imino]methyl}amino)-5-formylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 199536-07-7
methyl 3-({[(tert-butoxycarbonyl)amino][(tert-butoxycarbonyl)imino]methyl}amino)-5-(hydroxymethyl)benzoate

: 199536-09-9
methyl 3-({[(tert-butoxycarbonyl)amino][(tert-butoxycarbonyl)imino]methyl}amino)-5-formylbenzoate

Guidance literature:: With pyridinium chlorochromate; In dichloromethane; for 16h; Ambient temperature;
DOI:10.1021/jm970479e

Reference yield:

: 1955-46-0
5-nitro-1,3-benzenedicarboxylic acid, monomethyl ester

: 199536-09-9
methyl 3-({[(tert-butoxycarbonyl)amino][(tert-butoxycarbonyl)imino]methyl}amino)-5-formylbenzoate

Guidance literature:: Multi-step reaction with 5 steps

1: oxalyl chloride, DMF, pyridine / tetrahydrofuran; acetonitrile / 1 h / -30 °C

2: CuI, LiAlH3)3>3 / tetrahydrofuran; acetonitrile / 0.17 h / -78 °C

3: 78 percent / H₂ / PtO₂ / methanol / 0.5 h / 2585.7 Torr

4: 86 percent / Et₃N, HgCl₂ / dimethylformamide / 16 h / Ambient temperature

5: 82 percent / pyridinium chlorochromate / CH₂Cl₂ / 16 h / Ambient temperature

With pyridine; copper(l) iodide; oxalyl dichloride; hydrogen; lithium tri-t-butoxyaluminum hydride; triethylamine; N,N-dimethyl-formamide; pyridinium chlorochromate; mercury dichloride; platinum(IV) oxide; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jm970479e

Reference yield:

: 1955-04-0
methyl 5-nitro-3-chloroformylbenzoate

: 199536-09-9
methyl 3-({[(tert-butoxycarbonyl)amino][(tert-butoxycarbonyl)imino]methyl}amino)-5-formylbenzoate

Guidance literature:: Multi-step reaction with 4 steps

1: CuI, LiAlH3)3>3 / tetrahydrofuran; acetonitrile / 0.17 h / -78 °C

2: 78 percent / H₂ / PtO₂ / methanol / 0.5 h / 2585.7 Torr

3: 86 percent / Et₃N, HgCl₂ / dimethylformamide / 16 h / Ambient temperature

4: 82 percent / pyridinium chlorochromate / CH₂Cl₂ / 16 h / Ambient temperature

With copper(l) iodide; hydrogen; lithium tri-t-butoxyaluminum hydride; triethylamine; pyridinium chlorochromate; mercury dichloride; platinum(IV) oxide; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jm970479e