rhenium tetrachloride oxide

Base Information

• Chemical Name: rhenium tetrachloride oxide
• CAS No.: 13814-76-1
• Molecular Formula: Cl₄ORe
• Molecular Weight: 344.018
• Mol file: 13814-76-1.mol

Synonyms:Rheniumchloride oxide (ReOCl4) (6CI,7CI,8CI);Rhenium oxytetrachloride;Rheniumoxytetrachloride (ReOCl4);Rhenium tetrachloride monoxide;Rheniumtetrachloride oxide;Tetrachlorooxorhenium;Tetrachlorooxorhenium(VI);

Chemical Property of rhenium tetrachloride oxide

Chemical Property:

• Melting Point: 29.3°C
• Boiling Point: 223°C
• PSA: 17.07000
• LogP: 2.63920

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of rhenium tetrachloride oxide

There total 17 articles about rhenium tetrachloride oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

rhenium(V) chloride (13596-35-5) + oxygen (80937-33-3) → chlorotrioxorhenium + rhenium oxytetrachloride (13814-76-1,204864-46-0)

Guidance literature:

250°C, under (N2), 1 atm; destn., vacuum line;

DOI:10.1039/DT9800002467

Reference yield: 40.0%

rhenium(IV) sulfide (12038-63-0) → chlorotrioxorhenium + rhenium oxytetrachloride (204864-46-0,13814-76-1)

Guidance literature:

With oxygen; chlorine; In neat (no solvent); Cl2 : O2 = 1:3;;

Reference yield: 31.0%

aluminium trichloride (7446-70-0) + chlorotrioxorhenium → (rhenium trichloride dioxide)2 + rhenium oxytetrachloride (13814-76-1,204864-46-0)

Guidance literature:

In neat (no solvent); ReOCl3 combined with AlCl3; after 30 min transferred under vac. at -196°C into trap; CFCl3 condensed onto mixt.; slowly cooled to -78°C; elem. anal.;

DOI:10.1002/anie.200504468

upstream raw materials:

rhenium(V) chloride

oxygen

boron trichloride

aluminium trichloride

Downstream raw materials:

tetramesityloxorhenium(VI)

trans-tetraphenoxobis(trimethylphosphine)rhenium(IV)