trans-{PtH(CH₂CN)(PEt₃)2}

Base Information

• Chemical Name: trans-{PtH(CH₂CN)(PEt₃)2}
• CAS No.: 118831-46-2
• Molecular Formula: C₁₄H₃₃NP₂Pt
• Molecular Weight: 472.45
• Mol file: 118831-46-2.mol

Synonyms:trans-{PtH(CH₂CN)(PEt₃)2}

Chemical Property of trans-{PtH(CH₂CN)(PEt₃)2}

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of trans-{PtH(CH₂CN)(PEt₃)2}

There total 3 articles about trans-{PtH(CH₂CN)(PEt₃)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

cis-dichlorobis(triethylphosphine)platinum(II) (13965-02-1,14177-93-6,15692-07-6) + chlorobenzene (108-90-7) → trans-bis(triethylphosphino)phenylchloro platinum(II) + trans-chlorohydridobis(triethylphosphine)platinum(II) (16842-17-4,20436-52-6,89254-73-9) + trans-{PtH(CH2CN)(PEt3)2} (118831-46-2)

Guidance literature:

In chlorobenzene; acetonitrile; Electrolysis; preelectrolyzing solvents/TBAP, adding cis-(PtCl2(PEt3)2), electrolyzing at -2.1 V to near zero current (Ar); filtering, evapg., adding charcoal, extg. (benzene), filtering, concg., chromy. (alumina, benzene/hexane), slow evapg.;

DOI:10.1021/om00106a032

Reference yield: 38.0%

trans-chlorohydridobis(triethylphosphine)platinum(II) (16842-17-4,20436-52-6,89254-73-9) + tetrabutylammonium perchlorate (1923-70-2) → 1-butylene (106-98-9,9003-28-5) + trans-{PtH(CH2CN)(PEt3)2} (118831-46-2) + tributyl-amine (102-82-9) + platinum (7440-06-4)

Guidance literature:

In acetonitrile; benzene; byproducts: H2; Electrolysis; electrochemically reducing trans-(PtH(Cl)(PEt3)2) at -2.1 V vs Ag/AgCl in CH3CN/C6H6 (5/2, v/v), terminating electrolysis at constancy of current; 36% of hydrido complex recovered; 31P NMR;

DOI:10.1021/om00106a032

Reference yield:

trans-chlorohydridobis(triethylphosphine)platinum(II) (16842-17-4,20436-52-6,89254-73-9) → trans-{PtH(CH2CN)(PEt3)2} (118831-46-2) + trans-{PtCH3(CN)(PEt3)2} (22289-45-8) + platinum (7440-06-4)

Guidance literature:

In acetonitrile; benzene; Electrolysis; electrochemically reducing trans-(PtH(Cl)(PEt3)2) at -2.1 V vs Ag/AgCl in CH3CN/C6H6 (5/2, v/v), terminating electrolysis at constancy of current, standing sealed in vacuo for several weeks; 31P NMR;

DOI:10.1021/om00106a032

upstream raw materials:

trans-chlorohydridobis(triethylphosphine)platinum(II)

tetrabutylammonium perchlorate

cis-dichlorobis(triethylphosphine)platinum(II)

chlorobenzene