[MoH₂(formato)((Ph₂PCH₂CH₂P(Ph)C₆H₄-o)2(Ph)Si-P,P,P,P,Si)]

Base Information

• Chemical Name: [MoH₂(formato)((Ph₂PCH₂CH₂P(Ph)C₆H₄-o)2(Ph)Si-P,P,P,P,Si)]
• CAS No.: 403482-55-3
• Molecular Formula: C₅₉H₅₄MoO₂P₄Si
• Molecular Weight: 1043
• Mol file: 403482-55-3.mol

Synonyms:[MoH₂(formato)((Ph₂PCH₂CH₂P(Ph)C₆H₄-o)2(Ph)Si-P,P,P,P,Si)]

Chemical Property of [MoH₂(formato)((Ph₂PCH₂CH₂P(Ph)C₆H₄-o)2(Ph)Si-P,P,P,P,Si)]

Chemical Property:

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Technology Process of [MoH₂(formato)((Ph₂PCH₂CH₂P(Ph)C₆H₄-o)2(Ph)Si-P,P,P,P,Si)]

There total 2 articles about [MoH₂(formato)((Ph₂PCH₂CH₂P(Ph)C₆H₄-o)2(Ph)Si-P,P,P,P,Si)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

[MoH3([Ph2PCH2CH2P(Ph)-C6H4-o]2(Ph)Si-P,P,P,P,Si)] + carbon dioxide (124-38-9,18923-20-1) → [MoH2(formato)((Ph2PCH2CH2P(Ph)C6H4-o)2(Ph)Si-P,P,P,P,Si)] (403482-55-3)

Guidance literature:

In toluene; High Pressure; 17 atm CO2, room temp.;

DOI:10.1039/b107837m

Reference yield: 7.0%

formic acid (64-18-6) + [MoH3([Ph2PCH2CH2P(Ph)-C6H4-o]2(Ph)Si-P,P,P,P,Si)] → [MoH2(formato)((Ph2PCH2CH2P(Ph)C6H4-o)2(Ph)Si-P,P,P,P,Si)] (403482-55-3)

Guidance literature:

In toluene; byproducts: dihydrogen; (Ar); using Schlenk techniques; addn. of formic acid (2 equiv.) to stirred soln. of MoH3((C6H5)2PCH2CH2P(C6H5)C6H4)2(Ph)Si in toluene with a syringe at ambient temp., stirring for 10 h; addn. of excess hexane, pptn., removal of supernatant, drying of ppt. under reduced pressure, washing with hexane, drying in vac.;

DOI:10.1021/om200646c

upstream raw materials:

formic acid

carbon dioxide