1,4-di[4-((E)-3-tert-butyldiphenylsilyl-6,6-dibromo-4-chloro-hexa-3,5-dien-1-ynyl)-phenyl]-buta-1,3-diyne

Base Information

Chemical Name:1,4-di[4-((E)-3-tert-butyldiphenylsilyl-6,6-dibromo-4-chloro-hexa-3,5-dien-1-ynyl)-phenyl]-buta-1,3-diyne
CAS No.:1191093-40-9
Molecular Formula:C₆₀H₄₈Br₄Cl₂Si₂
Molecular Weight:1215.73
Hs Code.:

Synonyms:1,4-di[4-((E)-3-tert-butyldiphenylsilyl-6,6-dibromo-4-chloro-hexa-3,5-dien-1-ynyl)-phenyl]-buta-1,3-diyne

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Chemical Property of 1,4-di[4-((E)-3-tert-butyldiphenylsilyl-6,6-dibromo-4-chloro-hexa-3,5-dien-1-ynyl)-phenyl]-buta-1,3-diyne

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Technology Process of 1,4-di[4-((E)-3-tert-butyldiphenylsilyl-6,6-dibromo-4-chloro-hexa-3,5-dien-1-ynyl)-phenyl]-buta-1,3-diyne

There total 1 articles about 1,4-di[4-((E)-3-tert-butyldiphenylsilyl-6,6-dibromo-4-chloro-hexa-3,5-dien-1-ynyl)-phenyl]-buta-1,3-diyne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 558-13-4
carbon tetrabromide

: 1191093-39-6
1,4-di[4-((E)-3-tert-butyldiphenylsilyl-4-chloro-5-oxo-pent-3-en-1-ynyl)-phenyl]-buta-1,3-diyne

: 1191093-40-9
1,4-di[4-((E)-3-tert-butyldiphenylsilyl-6,6-dibromo-4-chloro-hexa-3,5-dien-1-ynyl)-phenyl]-buta-1,3-diyne

Guidance literature:: carbon tetrabromide; With triphenylphosphine; In dichloromethane; at 0 ℃; for 1h; Inert atmosphere;

1,4-di[4-((E)-3-tert-butyldiphenylsilyl-4-chloro-5-oxo-pent-3-en-1-ynyl)-phenyl]-buta-1,3-diyne; In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere;
DOI:10.1021/jo901766p

Reference yield: 55.0%

: 75-77-4
chloro-trimethyl-silane

: 1191093-40-9
1,4-di[4-((E)-3-tert-butyldiphenylsilyl-6,6-dibromo-4-chloro-hexa-3,5-dien-1-ynyl)-phenyl]-buta-1,3-diyne

: 1191093-41-0
1,4-di[4-((E)-3-tert-butyldiphenylsilyl-4-chloro-6-trimethylsilyl-hex-3-ene-1,5-diynyl)-phenyl]-buta-1,3-diyne

Guidance literature:: With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;
DOI:10.1021/jo901766p